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Electrochemical Corrosion Behavior of Monel Alloy in Carbonate Melts

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Abstract

The interaction of the monel alloy and its corrosion resistance in a melt of alkali metal carbonates in an oxidizing atmosphere was studied. The selectivity of alloy dissolution and modification of the electrode surface after storage at a constant anode potential were analyzed. The generation and development of local corrosion defects (pit corrosion, intercrystallite corrosion, corrosion cracking) on monel alloy (70% nickel, 28% copper), copper, and nickel electrodes in the molten eutectic of lithium, sodium, and potassium carbonates at a working temperature of 773 K were studied. The anode polarization was accompanied by a change in the state of the electrode surface.

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Correspondence to E. V. Nikitina.

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Original Russian Text © E.V. Nikitina, N.A. Kazakovtseva, M.A. Maikov, V.B. Malkov, E.A. Karfidov, A.Yu. Chuikin, 2018, published in Elektrokhimiya, 2018, Vol. 54, No. 9, pp. 801–805.

Published on the basis of materials of the First International Conference on Intelligent Technologies in Power Engineering, Yekaterinburg, 2017.

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Nikitina, E.V., Kazakovtseva, N.A., Maikov, M.A. et al. Electrochemical Corrosion Behavior of Monel Alloy in Carbonate Melts. Russ J Electrochem 54, 697–701 (2018). https://doi.org/10.1134/S1023193518090082

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  • DOI: https://doi.org/10.1134/S1023193518090082

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