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Electroactive Composite Pd–Polypyrrole and Its Catalytic Properties in the Reaction of Styryl Bromide Cyanation

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Abstract

A composite material in the form of powder is synthesized by a redox reaction in mixed aqueous solution of Pd(NH3)4Cl2 + pyrrole. The composite consists of polypyrrole globules with palladium nanoparticles uniformly distributed inside the latter. Being applied as a film on the electrode surface, both components of this material exhibit redox activity. Palladium particles inside the composite exhibit catalytic properties in cyanation of styryl bromides, a reaction widely used in fine organic synthesis.

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Authors and Affiliations

  1. Moscow State University, Faculty of Chemistry, Leninskie Gory, Moscow, 119992, Russia

    O. M. Nikitin, T. V. Magdesieva, O. V. Polyakova, P. K. Sazonov & M. A. Vorotyntsev

  2. Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast’, 142432, Russia

    K. V. Gor’kov, E. V. Zolotukhina & M. A. Vorotyntsev

  3. Mendeleeev University of Chemical Technology of Russia, Moscow, 125047, Russia

    M. A. Vorotyntsev

  4. ICMUB, UMR 6302 CNRS, Université de Bourgogne, Dijon, France

    M. A. Vorotyntsev

Authors
  1. O. M. Nikitin
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  2. T. V. Magdesieva
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  3. O. V. Polyakova
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  4. P. K. Sazonov
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  5. K. V. Gor’kov
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  6. E. V. Zolotukhina
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  7. M. A. Vorotyntsev
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Corresponding author

Correspondence to T. V. Magdesieva.

Additional information

Original Russian Text © O.M. Nikitin, T.V. Magdesieva, O.V. Polyakova, P.K. Sazonov, K.V. Gor’kov, E.V. Zolotukhina, M.A. Vorotyntsev, 2018, published in Elektrokhimiya, 2018, Vol. 54, No. 7, pp. 698–702.

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Nikitin, O.M., Magdesieva, T.V., Polyakova, O.V. et al. Electroactive Composite Pd–Polypyrrole and Its Catalytic Properties in the Reaction of Styryl Bromide Cyanation. Russ J Electrochem 54, 608–611 (2018). https://doi.org/10.1134/S1023193518070066

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  • DOI: https://doi.org/10.1134/S1023193518070066

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