Abstract
Calix[4]arenesulfonic acid complexation with perchloric acid is studied. The stoichiometric composition of the complex is shown to be calix[4]arene/HClO4 = 1/1. The complex is most stable against humidity changes as far as its proton-conducting properties are concerned. Its specific proton conductivity varies from 3 × 10–3 to 5 × 10–2 S/cm; the conductivity activation energy is 0.16 ± 0.04 eV. The studying of the effect of HClO4 amount on the samples’ physico-chemical properties at low humidity showed the proton transfer in the material to be determined by the crystallites’ bulk, rather than surface, characteristics.
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Original Russian Text © L.V. Shmygleva, R.R. Kayumov, A.I. Karelin, Yu.A. Dobrovol’skii, 2018, published in Elektrokhimiya, 2018, Vol. 54, No. 5, pp. 469–476.
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Shmygleva, L.V., Kayumov, R.R., Karelin, A.I. et al. Effect of Perchloric Acid on Proton-Conducting Properties of Sulfonated Calix[4]Arene. Russ J Electrochem 54, 409–414 (2018). https://doi.org/10.1134/S1023193518050075
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DOI: https://doi.org/10.1134/S1023193518050075