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Electrosynthesis of Н2О2 from О2 in Gas Diffusion Electrodes Based on Black СН600

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Abstract

Furnace black СН600 was studied as a catalyst for electrosynthesis of Н2О2 from О2 in a gas diffusion electrode in alkaline and acidic solutions. The texture properties of the starting black СН600 and gas diffusion electrodes (GDEs) based on it were determined by the low-temperature nitrogen adsorption (LTNA) method. The rate constants of Н2О2 decomposition on black and its mixtures with fluoroplast-4D in acidic and alkaline solutions of electrolyte were calculated. The process selectivity γ (the current fraction spent on the two-electron reduction of oxygen), kinetic parameters of oxygen reduction, and double-layer capacity of the СН600-based GDE were determined. Data on the kinetics of hydrogen peroxide accumulation during electrosynthesis from oxygen in СН600-based GDE in acidic and alkaline solutions were obtained.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russia

    V. L. Kornienko, G. A. Kolyagin, G. V. Kornienko & V. A. Parfenov

  2. Siberian State Technological University, Krasnoyarsk, 660049, Russia

    G. V. Kornienko

  3. Scientific and Technological Center of Carbon Materials, Omsk, 644049, Russia

    A. A. Petin

Authors
  1. V. L. Kornienko
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  2. G. A. Kolyagin
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  3. G. V. Kornienko
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  4. V. A. Parfenov
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  5. A. A. Petin
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Correspondence to V. L. Kornienko.

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Original Russian Text © V.L. Kornienko, G.A. Kolyagin, G.V. Kornienko, V.A. Parfenov, A.A. Petin, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 12, pp. 1487–1494.

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Kornienko, V.L., Kolyagin, G.A., Kornienko, G.V. et al. Electrosynthesis of Н2О2 from О2 in Gas Diffusion Electrodes Based on Black СН600. Russ J Electrochem 53, 1307–1313 (2017). https://doi.org/10.1134/S1023193517120059

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  • DOI: https://doi.org/10.1134/S1023193517120059

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