Skip to main content
SpringerLink
Log in

Effect of Surfactants on Electrodeposition of the Sn–Ni Alloy from Oxalate Solutions

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The effects of surfactants on the electrolytic deposition of tin–nickel alloys from oxalate–ammonium electrolytes were determined. The adsorption of the nonionic surfactant at the interface decreases the rate of charge transfer across the interface. As a result, the electrochemical stage of the electroreduction of metals slows down, and the alloy is deposited in the form of shiny finely crystalline coatings. The range of optimum surfactant concentrations in the oxalate–ammonium electrolyte was determined based on the simulation of the interface impedance obtained during the alloy deposition and the electron microscopy studies of the obtained coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rudnik, E., J. Electroanal. Chem., 2014, vol. 726, p. 97.

    Article  CAS  Google Scholar 

  2. Lačnjevac, U., Jović, B.M., and Jović, V.D., J. Electrochem. Soc., 2012, vol. 159, no. 5, p. 310.

    Article  Google Scholar 

  3. Jović, B.M., Lačnjevac, U., Krstajić, N.V., and Jović, V.D., Electrochim. Acta, 2013, vol. 114, p. 813.

    Article  Google Scholar 

  4. Du, Z., Zhang, S., Zhao, J., Jiang, T., and Bai, Z., Int. J. Electrochem. Sci., 2012, vol. 7, p. 1180.

    CAS  Google Scholar 

  5. Vyacheslavov, P.M., Elektroliticheskoe osazhdenie splavov (Electrolytic Deposition of Alloys), Leningrad: Mashinostroenie, 1986.

    Google Scholar 

  6. Zenin, V.V., Spiridonov, B.A., Berezina, N.N., and Kochergin, A., Tekhnol. Elektr. Prom., 2007, no. 7, p. 32.

    Google Scholar 

  7. Shekhanov, R.F., Gridchin, S.N., and Balmasov, A.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Teknol., 2013, vol. 56, no. 10, p. 95.

    CAS  Google Scholar 

  8. Shekhanov, R.F., Gridchin, S.N., and Balmasov, A.V., Surf. Eng. Appl. Electrochem., 2016, vol. 52, no. 2, p. 152.

    Article  Google Scholar 

  9. Spiridonov, B.A. and Berezina, N.N., Prot. Met., 2004, vol. 40, no. 1, p. 85.

    Article  CAS  Google Scholar 

  10. Sluyters-Rehbach, M., Pure Appl. Chem., 1994, vol. 66, p. 1831.

    Article  CAS  Google Scholar 

  11. Stoynov, Z.B., Grafov, B.M., Savvova-Stoynova, B.S., and Elkin, V.V., Elektrikhimicheskii impedans (Electrochemical Impedance), Moscow: Nauka, 1991.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

    R. F. Shekhanov, A. V. Balmasov & S. N. Gridchin

  2. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia

    S. M. Kuz’min

  3. Ivanovo State Power University, Ivanovo, 153003, Russia

    S. M. Kuz’min

Authors
  1. R. F. Shekhanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. M. Kuz’min
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Balmasov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. N. Gridchin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. F. Shekhanov.

Additional information

Original Russian Text © R.F. Shekhanov, S.M. Kuz’min, A.V. Balmasov, S.N. Gridchin, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 11.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shekhanov, R.F., Kuz’min, S.M., Balmasov, A.V. et al. Effect of Surfactants on Electrodeposition of the Sn–Ni Alloy from Oxalate Solutions. Russ J Electrochem 53, 1274–1280 (2017). https://doi.org/10.1134/S1023193517110131

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193517110131

Keywords

Search

Navigation