Abstract
The results of studying characteristics of potentiometric DP-sensors (sensors with the Donnan potential as their analytical signal) are presented for alkaline solutions of a sulfur-containing amino acid with perfluorosulfonic cation exchange membranes subjected to thermal treatment and mechanical deformation at different relative humidity. Correlation between the distribution of sensitivity of DP-sensors towards cations and anions and diffusion permeability of membranes was found. A multisensor system including two DP-sensors based on membranes with optimized properties and a glass electrode for codetermination of potassium cations and amino acid anions and zwitterions in solutions at pH >7 are developed.
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Original Russian Text © A.V. Parshina, E.Yu. Safronova, T.S. Titova, D.V. Safronov, A.A. Lysova, O.V. Bobreshova, A.B. Yaroslavtsev, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 11.
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Parshina, A.V., Safronova, E.Y., Titova, T.S. et al. Potentiometric Cross-Sensitive Sensors Based on Perfluorinated Membranes Treated at Different Relative Humidity for Codetermination of Cations and Anions in Alkaline Solutions of Amino Acids. Russ J Electrochem 53, 1294–1299 (2017). https://doi.org/10.1134/S1023193517110118
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DOI: https://doi.org/10.1134/S1023193517110118