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Electric double layer on renewable liquid (Cd–Ga) electrode in dimethylformamide solutions

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Abstract

The double-layer characteristics on a renewable liquid (Cd–Ga) electrode (0.3 at % Cd) in dimethylformamide (DMF) solutions of various electrolytes are studied by the methods of differential capacitance and open-circuit streaming electrode. The zero-charge potentials unaffected by specific adsorption of ions and the parameters characterizing the (Cd–Ga)–DMF chemisorptive interaction (chemisorption potential drop of solvent and two-dimensional pressure of chemisorbed DMF dipoles) are determined. The results are compared with similar results for the (Cd–Ga)/gamma-butyrolactone (GBL) interface. The energy of (Cd–Ga)–solvent chemisorptive interaction increases with the transition from GBL to DMF due to the increase in the donor number of solvent. The adsorbability of halide ions at the (Cd–Ga)/DMF interface is judged based on the PZC shift in 0.1 М solutions of LiCl, LiBr, and LiI with respect to the PZC in solutions of a surface-inactive electrolyte. On the (Cd–Ga)/DMF interface, the inverted series of surface activity of halide ions is observed. Whereas on Hg and Bi electrodes the surface activity increases in the series Cl– < Br– < I–, on the (Cd–Ga) electrode and also on Ga and (In–Ga) electrodes the activity varies in the inverted sequence I‒ < Br– < Cl–.

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References

  1. Emets, V.V. and Damaskin, B.B., Russ. J. Electrochem., 2009, vol. 45, p. 45.

    Article  CAS  Google Scholar 

  2. Emets, V.V. and Damaskin, B.B., J. Electroanal. Chem., 2007, vol. 600, p. 191.

    Article  CAS  Google Scholar 

  3. Emets, V.V., Mel’nikov, A.A., and Damaskin, B.B., Russ. J. Electrochem., 2016, vol. 52, p. 7.

    Article  CAS  Google Scholar 

  4. Gutman, V., Khimiya koordinatsionnykh soedinenii v nevodnykh rastvorakh (Chemistry of Coordination Compounds in Nonaqueous Solutions), Moscow: Mir, 1968.

    Google Scholar 

  5. Bagotskaya, I.A., Emets, V.V., Boitsov, V.G., and Kazarinov, V.E., Elektrokhimiya, 1988, vol. 24, p. 1145.

    CAS  Google Scholar 

  6. Emets, V.V. and Damaskin, B.B., Russ. J. Electrochem., 2010, vol. 46, p. 1036.

    Article  CAS  Google Scholar 

  7. Emets, V.V. and Damaskin, B.B., Russ. J. Electrochem., 2011, vol. 47, p. 89.

    Article  CAS  Google Scholar 

  8. Fawcett, W.R., Ikeda, B.N., and Sellan, J.B., Can. J. Chem. Interfacial Electrochem., 1979, vol. 57, p. 2268.

    CAS  Google Scholar 

  9. Ivanova, R.V., Ganzhina, I.M., and Damaskin, B.B., Elektrokhimiya, 1970, vol. 6, p. 709.

    Google Scholar 

  10. Damaskin, B.B., Ganzhina, I.M., and Ivanova, R.V., Elektrokhimiya, 1970, vol. 6, p. 1540.

    CAS  Google Scholar 

  11. Petyarv, E.K. and Palm, U.V., Elektrokhimiya, 1975, vol. 11, p. 1584.

    Google Scholar 

  12. Petyarv, E.K. and Palm, U.V., Elektrokhimiya, 1976, vol. 12, p. 621.

    Google Scholar 

  13. Emets, V.V. and Damaskin, B.B., J. Electroanal. Chem., 2015, vol. 752, p. 82.

    Article  CAS  Google Scholar 

  14. Vaartnou, M. and Lust, E., J. Electroanal Chem., 2008, vol. 614, p. 1.

    Article  Google Scholar 

  15. Vaartnou, M., Nerut, J., and Lust, E., J. Solid State Electrochem., 2011, vol. 15, p. 1893.

    Article  Google Scholar 

  16. Emets, V.V., Damaskin, B.B., Bagotskaya, I.A., and Mishuk, V.Ya., Russ. J. Electrochem., 2000, vol. 36, p. 661.

    Article  CAS  Google Scholar 

  17. Emets, V.V. and Damaskin, B.B., J. Electroanal. Chem., 2000, vol. 491, p. 30.

    Article  CAS  Google Scholar 

  18. Emets, V.V. and Damaskin, B.B., J. Electroanal. Chem., 2012, vol. 667, p. 76.

    Article  CAS  Google Scholar 

  19. Gouy, G., J. Phys. Radium, 1910, vol. 9, p. 457.

    CAS  Google Scholar 

  20. Chapman, D., Philos. Mag., 1913, vol. 25, p. 475.

    Article  Google Scholar 

  21. Grahame, D., Chem. Rev., 1947, vol. 41, p. 441.

    Article  CAS  Google Scholar 

  22. Parsons, R. and Zobel, F.G.K., J. Electroanal. Chem., 1965, vol. 9, p. 333.

    CAS  Google Scholar 

  23. Emets, V.V. and Damaskin, B.B., Russ. J. Electrochem., 2000, vol. 36, p. 668.

    Article  CAS  Google Scholar 

  24. Emets, V.V., Kazarinov, V.E., and Bagotskaya, I.A., Russ. J. Electrochem., 1996, vol. 32, p. 1069.

    CAS  Google Scholar 

  25. Emets, V.V., Damaskin, B.B., and Kazarinov, V.E., Elektrokhimiya, 1995, vol. 31, p. 117.

    Google Scholar 

  26. Emets, V.V., Damaskin, B.B., and Kazarinov, V.E., Elektrokhimiya, 1995, vol. 31, p. 787.

    Google Scholar 

  27. Emets, V.V., Damaskin, B.B., and Kazarinov, V.E., Russ. J. Electrochem., 1996, vol. 32, p. 1062.

    CAS  Google Scholar 

  28. Bagotskaya, I.A., Damaskin, B.B., Emets, V.V., and Kazarinov, V.E., J. Electroanal. Chem., 1998, vol. 448, p. 229.

    Article  CAS  Google Scholar 

  29. Emets, V.V., Damaskin, B.B., and Kazarinov, V.E., Russ. J. Electrochem., 1999, vol. 35, p. 499.

    CAS  Google Scholar 

  30. Emets, V.V. and Damaskin, B.B., J. Electroanal. Chem., 2002, vol. 528, p. 57.

    Article  CAS  Google Scholar 

  31. Amokrane, S. and Badiali, J.P., J.Electroanal. Chem., 1989, vol. 266, p. 21.

    Article  CAS  Google Scholar 

  32. Amokrane, S. and Badiali, J.P., J. Electroanal. Chem., 1991, vol. 297, p. 377.

    Article  CAS  Google Scholar 

  33. Amokrane, S. and Badiali, J.P., in Modern Aspects of Electrochemistry, Bockris, J.O’M., Conway, B.E., and White, R.E., Eds., New York: Plenum, 1992.

  34. Trasatti, S., in Modern Aspects of Electrochemistry, White, R.E., Eds, New York: Kluwer Academic/Plenum, 1999, vol. 33, p. 1.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    V. V. Emets & A. A. Mel’nikov

  2. Moscow State University, Leninskie Gory, Moscow, 119991, Russia

    B. B. Damaskin

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  1. V. V. Emets
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  2. A. A. Mel’nikov
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  3. B. B. Damaskin
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Correspondence to V. V. Emets.

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Original Russian Text © V.V. Emets, A.A. Mel’nikov, B.B. Damaskin, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 2, pp. 131–139.

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Emets, V.V., Mel’nikov, A.A. & Damaskin, B.B. Electric double layer on renewable liquid (Cd–Ga) electrode in dimethylformamide solutions. Russ J Electrochem 53, 117–124 (2017). https://doi.org/10.1134/S1023193517020057

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