Skip to main content
SpringerLink
Log in

Electrochemical synthesis and study of poly(2,5-diarylamino-3,6-dichlorobenzoquinone) and its composite with multiwalled carbon nanotubes

  • Short Communications
  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

A procedure has been developed for electrochemical polymerization of dianiline dichlorobenzoquinone and electrosynthesis of a composite material based on poly(dianiline dichlorobenzoquinone) and multiwalled carbon nanotubes (MCNTs) in 1 M H2SO4. The introduction of a polymerization initiator (potassium hexachloroiridate IrCl6 2− (HCI)) accelerated the growth of the electrode coating. The introduction of MCNTs led to the creation of a current-conducting framework in the composite and an increase in the mass and electrochemical capacity of the electrode coating. The electrochemical behavior of the composite is similar to that of polyaniline (PAni), but includes the redox reaction of the chloranil substituents. The charging of the double electric layer makes a significant contribution to the electrochemical capacity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Shirakawa, H., McDiarmid, A., and Heeger, A., Chem. Commun., 2003, p. 1.

    Google Scholar 

  2. MacDiarmid, A.G., Angew. Chem., Int. Ed., 2001, vol. 40, p. 2581.

    Article  CAS  Google Scholar 

  3. Grätzel, M., Nature, 2001, vol. 414, no. 6861, p. 338.

    Article  Google Scholar 

  4. Negi, Y.S. and Adhyapak, P.V., J. Macromol. Sci., Polym. Rev., 2002, vol. 42, p. 35.

    Article  Google Scholar 

  5. Abalyaeva, V.V. and Efimov, O.N., Russ. J. Electrochem., 2010, vol. 46, p. 571.

    Article  CAS  Google Scholar 

  6. Abalyaeva, V.V. and Efimov, O.N., Russ. J. Electrochem., 2011, vol. 47, p. 1299.

    Article  CAS  Google Scholar 

  7. Abalyaeva, V.V. and Efimov, O.N., Russ. J. Electrochem., 2011, vol. 47, p. 1307.

    Article  CAS  Google Scholar 

  8. Šeděnkova, I., Trchova, M., Blinova, N.V., and Stejskal, Ja., Thin Solid Films, 2006, vol. 515, p. 1640.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432, Russia

    V. V. Abalyaeva & O. N. Efimov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119071, Russia

    A. V. Orlov, S. G. Kiseleva & G. P. Karpacheva

Authors
  1. V. V. Abalyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Orlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. G. Kiseleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. N. Efimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. P. Karpacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Abalyaeva.

Additional information

Original Russian Text © V.V. Abalyaeva, A.V. Orlov, S.G. Kiseleva, O.N. Efimov, G.P. Karpacheva, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 2, pp. 233–240.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abalyaeva, V.V., Orlov, A.V., Kiseleva, S.G. et al. Electrochemical synthesis and study of poly(2,5-diarylamino-3,6-dichlorobenzoquinone) and its composite with multiwalled carbon nanotubes. Russ J Electrochem 53, 210–216 (2017). https://doi.org/10.1134/S1023193517020021

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193517020021

Keywords

Search

Navigation