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The effect of counterion in polymer sulfonates on the synthesis and properties of poly-3,4-ethylenedioxythiophene

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Abstract

The electrochemical polymerization of 3,4-ethylenedioxythiophene (EDOT) in the presence of the salt and acid forms of polymer sulfonates with different polymer-chain flexibility is studied. The dependence of the rate of synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) on the nature of polysulfonate counterion that determines the type and distribution density of the charge in the polyelectrolyte chain is demonstrated. For the Н+ form of a rigid-chain polysulfonate, it is found that the specific interactions between parts of its macromolecules lead to destabilization of EDOT•+ radical cations, hinder the growth of PEDOT chains, and favor the formation of structures with the high degree of charge localization.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    O. D. Iakobson, O. L. Gribkova, A. A. Nekrasov & A. V. Vannikov

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  1. O. D. Iakobson
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  2. O. L. Gribkova
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  3. A. A. Nekrasov
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  4. A. V. Vannikov
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Correspondence to O. D. Iakobson.

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Original Russian Text © O.D. Iakobson, O.L. Gribkova, A.A. Nekrasov, A.V. Vannikov, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 12, pp. 1333–1344.

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Iakobson, O.D., Gribkova, O.L., Nekrasov, A.A. et al. The effect of counterion in polymer sulfonates on the synthesis and properties of poly-3,4-ethylenedioxythiophene. Russ J Electrochem 52, 1191–1201 (2016). https://doi.org/10.1134/S1023193516120132

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  • DOI: https://doi.org/10.1134/S1023193516120132

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