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Simulation of differential pulse polarography of irreversible EC mechanism

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Abstract

A reversible electrode reaction that is followed by totally irreversible chemical reaction is investigated theoretically. The influence of chemical reaction on two components of the net response of differential pulse polarogram is analyzed. It is demonstrated that this EC mechanism depends on two kinetic parameters and that their critical values can be used for the measurement of the rate constant of chemical reaction.

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References

  1. Galus, Z., Fundamentals of Electrochemical Analysis, Chichester Publ. Ellis Horwood Ltd., 1976.

    Google Scholar 

  2. Smith, D.E., Anal. Chem., 1963, vol. 35, p. 602.

    Article  CAS  Google Scholar 

  3. Ridgway, T.H., Van Duyne, R.P., and Reilley, C.N., J. Electroanal. Chem., 1972, vol. 34, p. 267.

    Article  CAS  Google Scholar 

  4. Matsuda, H., J. Electroanal. Chem., 1974, vol. 56, p. 165.

    Article  CAS  Google Scholar 

  5. Galvez, J., Robles, F., Zapata, J., and Park, S.M., Electrochim. Acta, 1990, vol. 35, p. 95.

    Article  CAS  Google Scholar 

  6. Lopez-Tenes, M., Molina, J.M., and Molina, A., Electroanalysis, 2004, vol. 16, p. 938.

    Article  CAS  Google Scholar 

  7. Galvez, J., Saura, R., and Molina, A., J. Electroanal. Chem., 1983, vol. 147, p. 53.

    Article  CAS  Google Scholar 

  8. Kim, M.H., Anal. Chem., 1987, vol. 59, p. 2136.

    Article  CAS  Google Scholar 

  9. Gimre, K.T., Whiteley R.V., and Guenther, C.M., J. Math. Chem., 2012, vol. 50, p. 805.

    Article  CAS  Google Scholar 

  10. Galvez, J. and Molina, A., J. Electroanal. Chem., 1980, vol. 110, p. 49.

    Article  CAS  Google Scholar 

  11. Bond, A.M., O’Halloran, R.J., Ružic, I., and Smith, D.E., J. Electroanal. Chem., 1982, vol. 132, p. 39.

    Article  CAS  Google Scholar 

  12. Nadjo, L. and Saveant, J.M., J. Electroanal. Chem., 1973, vol. 48, p. 113.

    Article  CAS  Google Scholar 

  13. Nicholson, R.S. and Shain, I., Anal. Chem., 1964, vol. 36, p. 706.

    Article  CAS  Google Scholar 

  14. Lovric, M., Komorsky-Lovric, Š., and Branica, M., Croat. Chem. Acta, 1993, vol. 66, p. 279.

    CAS  Google Scholar 

  15. Molina, A., Martinez-Ortiz, F., and Laborda, E., Int. J. Electrochem. Sci., 2009, vol. 4, p. 1395.

    CAS  Google Scholar 

  16. Galvez, J., Molina, A., and Serna, C., J. Electroanal. Chem., 1981, vol. 124, p. 201.

    Article  CAS  Google Scholar 

  17. Papadopoulos, N., Lemos, M.A.N.D.A., and Pombeiro, A.J.L., Anal. Chim. Acta, 1995, vol. 306, p. 107.

    Article  CAS  Google Scholar 

  18. Miles, A.B. and Compton, R.G., J. Phys. Chem. B, 2000, vol. 104, p. 5331.

    Article  CAS  Google Scholar 

  19. Miles, A.B. and Compton, R.G., J. Electroanal. Chem., 2001, vol. 499, p. 1.

    Article  CAS  Google Scholar 

  20. Mirceski, V., J. Electroanal. Chem., 2001, vol. 508, p. 138.

    Article  CAS  Google Scholar 

  21. Jadreško, D. and Zelić, M., J. Electroanal. Chem., 2014, vols. 714–715, p. 30.

    Article  Google Scholar 

  22. Hermolin, J., Talmor, D., and Kirowa-Eisner, E., J. Electroanal. Chem., 2000, vol. 491, p. 148.

    Article  CAS  Google Scholar 

  23. Corredor, M.C., Rodriguez Mellado, J.M., and Ruiz Montoya, M., Electrochim. Acta, 2006, vol. 51, p. 4302.

    Article  CAS  Google Scholar 

  24. Laviron, E., Meunier-Prest, R., and Mathieu, E., J. Electroanal. Chem., 1994, vol. 371, p. 251.

    Article  CAS  Google Scholar 

  25. Laviron, E., J. Electroanal. Chem., 1995, vol. 391, p. 187.

    Article  Google Scholar 

  26. Kim, M.H., Yan, L., Birke, R.L., and Czar, M.Z., Electroanalysis, 2003, vol. 15, p. 1541.

    Article  CAS  Google Scholar 

  27. Maletin, Y.A., Strizhakova, N.G., Kozachkov, S.G., and Cannon, R.D., J. Electroanal. Chem., 1995, vol. 398, p. 129.

    Article  Google Scholar 

  28. Galvez, J., J. Electroanal. Chem., 1998, vol. 452, p. 19.

    Article  CAS  Google Scholar 

  29. Zelić, M. and Jadreško, D., Electroanalysis, 2008, vol. 17, p. 1897.

    Google Scholar 

  30. Zelić, M. and Lovrić, M., Electroanalysis, 2011, vol. 23, p. 642.

    Google Scholar 

  31. Zelić, M., Pižeta, I., and Jadreško, D., Croat. Chem. Acta, 2012, vol. 85, p. 303.

    Article  Google Scholar 

  32. Komorsky-Lovric, Š., J. Electroanal. Chem., 2015, vol. 748, p. 58.

    Article  CAS  Google Scholar 

  33. Cižmek, L., Komorsky-Lovric, Š., and Lovric, M., Chem. Electro. Chem., 2015, vol. 2, p. 2027.

    Google Scholar 

  34. Olmstead, M.L. and Nicholson, R.S., J. Electroanal. Chem., 1968, vol. 16, p. 145.

    Article  CAS  Google Scholar 

  35. Bieniasz, L. K., Modelling Electroanalytical Experiments by the Integral Equation Method, Berlin Springer, 2015.

    Book  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Marine and Environmental Research, “Ruđer Bošković” Institute, 10000, Zagreb, Hrvatska (Croatia)

    Milivoj Lovric

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  1. Milivoj Lovric
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Correspondence to Milivoj Lovric.

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Published in Russian in Elektrokhimiya, 2016, Vol. 52, No. 10, pp. 1053–1058.

The article is published in the original.

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Lovric, M. Simulation of differential pulse polarography of irreversible EC mechanism. Russ J Electrochem 52, 938–942 (2016). https://doi.org/10.1134/S1023193516100086

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  • DOI: https://doi.org/10.1134/S1023193516100086

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