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Electrochemical noise spectroscopy: Method of secondary Chebyshev spectrum

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Abstract

A new method of electrochemical noise diagnostics is presented: the method of the secondary Chebyshev spectrum based on the splitting of an individual spectral line in the primary Chebyshev spectrum with formation of a system of spectral lines of the secondary Chebyshev spectrum. Algorithm for calculation of the secondary Chebyshev spectrum is developed. The suggested method based on analysis of noises measured in a specific electrochemical system is tested. It is shown that the new method allows determining the differences in the state of the electrochemical system more reliably, than the method of primary Chebyshev noise spectra.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    A. L. Klyuev, A. D. Davydov & B. M. Grafov

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 132432, Russia

    Yu. A. Dobrovolskii, A. E. Ukshe & E. A. Astaf’ev

Authors
  1. A. L. Klyuev
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  2. A. D. Davydov
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  3. B. M. Grafov
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  4. Yu. A. Dobrovolskii
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  5. A. E. Ukshe
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  6. E. A. Astaf’ev
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Corresponding author

Correspondence to A. D. Davydov.

Additional information

Original Russian Text © A.L. Klyuev, A.D. Davydov, B.M. Grafov, Yu.A. Dobrovolskii, A.E. Ukshe, E.A. Astaf’ev, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 10, pp. 1123–1127.

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Klyuev, A.L., Davydov, A.D., Grafov, B.M. et al. Electrochemical noise spectroscopy: Method of secondary Chebyshev spectrum. Russ J Electrochem 52, 1001–1005 (2016). https://doi.org/10.1134/S1023193516100062

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  • DOI: https://doi.org/10.1134/S1023193516100062

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