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Electrosynthesis and biological properties of persulfate–chloride solutions

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Abstract

A method for electrochemical synthesis of medical solutions for oxidation of toxic substances in the human organism has been developed. The method is based on electrooxidation of sodium sulfate in the presence of chloride and NaOH microadditions (in amounts that provide рН 13) in a filter-press membrane electrolyzer. A diagram is presented for choosing the optimum ratio between the current density and the flow rate of electrolyte during the electrosynthesis of a medical solution. The use of an electrolyte of the suggested composition under the optimum electrosynthesis conditions leads to solutions with physiological рН values (7.2–7.4) and high oxidative ability with respect to Micrococcus sp. and Staphylococcus coag (–), but there was no injuring effect on blood cells.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    V. N. Andreev & A. D. Davydov

  2. Mendeleev University of Chemical Technology of Russia, Moscow, Russia

    M. M. Goldin & A. K. Evseev

  3. Sklifosovsky Research Institute of Emergency Medicine, Moscow, Russia

    Yu. A. Kurylkin

Authors
  1. V. N. Andreev
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  2. M. M. Goldin
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  3. A. K. Evseev
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  4. A. D. Davydov
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  5. Yu. A. Kurylkin
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Corresponding author

Correspondence to M. M. Goldin.

Additional information

Original Russian Text © V.N. Andreev, M.M. Goldin, A.K. Evseev, A.D. Davydov, Yu.A. Kurylkin, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 10, pp. 1113–1117.

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Andreev, V.N., Goldin, M.M., Evseev, A.K. et al. Electrosynthesis and biological properties of persulfate–chloride solutions. Russ J Electrochem 52, 992–995 (2016). https://doi.org/10.1134/S1023193516100025

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  • DOI: https://doi.org/10.1134/S1023193516100025

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