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Highly active and stable catalysts based on nanotubes and modified platinum for fuel cells

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Abstract

Results on the development of new cathodic catalysts (monoplatinum and cobalt-modified platinum) applied on carbon nanotubes are shown. By means of a complex of electrochemical and structural techniques, it is shown that as regards their activity under model conditions and within membrane-electrode assembles, the catalysts synthesized by the polyol method are close to commercial monoplatinum systems with the same mass content of platinum (20 wt %) and their corrosion stability is double that of commercial catalysts. Platinum modified with cobalt is characterized by still higher stability, which allows considering these catalytic systems as the candidates to be used in fuel cells after the corresponding optimization.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. A. Bogdanovskaya, M. R. Tarasevich, M. V. Radina, G. V. Zhutaeva & A. V. Kuzov

  2. Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    E. M. Kol’tsova & N. N. Gavrilova

Authors
  1. V. A. Bogdanovskaya
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  2. E. M. Kol’tsova
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  3. M. R. Tarasevich
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  4. M. V. Radina
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  5. G. V. Zhutaeva
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  6. A. V. Kuzov
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  7. N. N. Gavrilova
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Corresponding author

Correspondence to V. A. Bogdanovskaya.

Additional information

Original Russian Text © V.A. Bogdanovskaya, E.M. Kol’tsova, M.R. Tarasevich, M.V. Radina, G.V. Zhutaeva, A.V. Kuzov, N.N. Gavrilova, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 8, pp. 810–822.

Published on the basis of the materials of III All-Russia Conference “Fuel Cells and Power Plants on Their Basis”, Chernogolovka, 2015.

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Bogdanovskaya, V.A., Kol’tsova, E.M., Tarasevich, M.R. et al. Highly active and stable catalysts based on nanotubes and modified platinum for fuel cells. Russ J Electrochem 52, 723–734 (2016). https://doi.org/10.1134/S1023193516080036

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  • DOI: https://doi.org/10.1134/S1023193516080036

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