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Preparation of cobalt polyporphine and its catalytic properties in oxygen electroreduction

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Abstract

A new member of the polyporphine series—cobalt polyporphine of type I (pCoP-I)—was prepared from the starting magnesium polyporphine of type I (pMgP-I) by ion exchange, i.e. by sequential processing of the pMgP-I polymer film on the electrode surface with solutions of trifluoroacetic acid (forming metalfree polyporphine of type I, pH2P-I) and cobalt(II) acetate in organic solvents. The completeness of each stage of ion exchange can be judged from the change in the electrochemical and spectral characteristics of the obtained polymer films of unsubstituted porphine (?H2P-I) and cobalt porphine (pCoP-I) of type I. Oxidative transformation of this polyporphine pCoP-I was performed, which led to the formation of additional bonds between the neighboring porphine units in the polymer film (transition of polymer of type I into polymer of type II, pCoP-II). The behavior of the polymer films of cobalt polyporphine of types I and II in oxygen electroreduction was studied. The films showed catalytic activity in this process.

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References

  1. Handbook, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., vols. 1–20, Academic Press, 2000.

  2. Lucas, D., Dime, A.K.D., Rousselin, Y., and Mugnier, Y., Dalton Trans., 2010, vol. 39, p. 2404.

    Article  Google Scholar 

  3. de Medeiros, M.A.C., Gorgy, K., Deronzier, A., and Cosnier, S., Mater. Sci. Eng., C, 2008, vol. 28, p. 731.

    Article  Google Scholar 

  4. Tesakova, M.V., Popov, I.A., Sheinin, V.B., Semeikin, A.S., Parfenyuk, V.I., and Koifman, O.I., Macroheterocycles, 2013, vol. 6, p. 152.

    Article  CAS  Google Scholar 

  5. Zhutaeva, G.V., Tarasevich, M.R., Radina, M.V., and Chernyshova, I.S., Russ. J. Electrochem., 2009, vol. 45, p. 1080.

    Article  CAS  Google Scholar 

  6. Tarasevich, M.R., Beketaeva, L.A., Efremov, B.N., Zagudaeva, N.M., Kuznetsova, L.N., Rybalka, K.V., and Sosenkin, V.E., Russ. J. Electrochem., 2004, vol. 40, p. 542.

    Article  CAS  Google Scholar 

  7. Bogdanovskaya, V.A., Beketaeva, L.A., Rybalka, K.V., Efremov, B.N., Zagudaeva, N.M., Sakashita, M., Iidzima, T., and Ismagilov, Z.R., Russ. J. Electrochem., 2008, vol. 44, p. 293.

    Article  CAS  Google Scholar 

  8. Vershinina, I.A., Gornukhina, O.V., Pimkov, I.V., and Golubchikov, O.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2009, vol. 52, p. 83.

    CAS  Google Scholar 

  9. Vorotyntsev, M.A., Konev, D.V., Devillers, C.H., Bezverkhyy, I., and Heintz, O., Electrochim. Acta, 2010, vol. 55, p. 6703.

    Article  CAS  Google Scholar 

  10. Vorotyntsev, M.A., Konev, D.V., Devillers, C.H., Bezverkhyy, I., and Heintz, O., Electrochim. Acta, 2011, vol. 56, p. 3436.

    Article  CAS  Google Scholar 

  11. Konev, D.V., Devillers, C.H., Lizgina, K.V., Baulin, V.E., and Vorotyntsev, M.A., J. Electroanal. Chem., 2015, vol. 737, p. 235.

    Article  CAS  Google Scholar 

  12. Yamaguchi, Y., Int. J. Quantum Chem., 2009, vol. 109, p. 1584.

    Article  CAS  Google Scholar 

  13. Konev, D.V., Vorotyntsev, M.A., Devillers, C.H., Zyubina, T.S., Zyubin, A.S., Lizgina, K.V., and Volkov, A.G., Russ. J. Electrochem., 2013, vol. 49, p. 753.

    Article  CAS  Google Scholar 

  14. Konev, D.V., Devillers, C.H., Lizgina, K.V., Zyubina, T.S., Zyubin, A.S., Valkova, L.A., and Vorotyntsev, M.A., Electrochim. Acta, 2014, vol. 122, pp. 3–10.

    Article  CAS  Google Scholar 

  15. Li, J., Diers, J.R., Seth, J., Yang, S.I., Bocian, D.F., Holten, D., and Lindsey, J.S., Org. Chem., 1999, vol. 64, p. 9090.

    Article  CAS  Google Scholar 

  16. Adler, A.D., Longo, F.R., Kampas, F., and Kim, J., J. Inorg. Nucl. Chem., 1970, vol. 32, p. 2443.

    Article  CAS  Google Scholar 

  17. Ogawa, T., Nishimoto, Y., Yoshida, N., Ono, N., and Osuka, A., Angew. Chem., Int. Ed. Engl., 1999, vol. 38, p. 176.

    Article  CAS  Google Scholar 

  18. Wu, Z.S., Chen, L., Liu, J., Parvez, K., Liang, H., Shu, J., Sachdev, H., Graf, R., Feng, X., and Mullen, K., Adv. Mater., 2014, vol. 26, p. 1450.

    Article  CAS  Google Scholar 

  19. Tarasevich, M.R. and Radyushkina, K.A., in Kataliz i elektrokataliz metalloporfirinami (Catalysis and Electrocatalysis with Metal Porphyrines), Moscow: Nauka, 1982, p. 168.

    Google Scholar 

  20. Tarasevich, M.R. and Orlov, S.B., in Elektrokhimiya polimerov (Polymer Electrochemistry), Moscow: Nauka, 1990, p. 238.

    Google Scholar 

  21. Tarasevich, M.R., Radyushkina, K.A., and Bogdanovskaya, V.A., in Elektrokhimiya porfirinov (Porphyrine Electrochemistry), Moscow: Nauka, 1991.

    Google Scholar 

  22. Zagal, J.H., Bedioui, F., and Dodelet, J.P., N4-Macrocyclic Metal Complexes, New York: Springer, 2006.

    Book  Google Scholar 

  23. Han, A., Jia, H., Ma, H., Ye, S., Wu, H., Lei, H., and Du, P., Phys. Chem. Chem. Phys., 2014, vol. 16, p. 11224.

    Article  CAS  Google Scholar 

  24. Hijazi, I., Bourgeteau, T., Cornut, R., Morozan, A., Filoramo, A., Leroy, J., and Campidelli, S., J. Am. Chem. Soc., 2014, vol. 136, p. 6348.

    Article  CAS  Google Scholar 

  25. Schaferling, M. and Bauerle, P., J. Mater. Chem., 2004, vol. 14, p. 1132.

    Article  Google Scholar 

  26. Cosnier, S., Gondran, C., Wessel, R., Montforts, F.P., and Wedel, M., J. Electroanal. Chem., 2000, vol. 488, p. 83.

    Article  CAS  Google Scholar 

  27. Bedioui, F., Devynck, J., and Bied-Charreton, C., Acc. Chem. Res., 1995, vol. 28, p. 30.

    Article  CAS  Google Scholar 

  28. Liddell, P.A., Gervaldo, M., Bridgewater, J.W., and Keirstead, A.E., Chem. Mater., 2008, vol. 20, p. 135.

    Article  CAS  Google Scholar 

  29. Paul-Roth, C., Rault-Berthelot, J., Simonneaux, G., and Poriel, C., J. Electroanal. Chem., 2006, vol. 597, p. 19.

    Article  CAS  Google Scholar 

  30. Medard, C., Lefevre, M., Dodelet, J.P., Jaouen, F., and Lindbergh, G., Electrochim. Acta, 2006, vol. 51, p. 3202.

    Article  CAS  Google Scholar 

  31. Konev, D.V., Istakova, O.I., Sereda, O.A., Shamraeva, M.A., Devillers, C.H., and Vorotyntsev, M.A., Electrochim. Acta, 2015, vol. 179, p. 315.

    Article  CAS  Google Scholar 

  32. Yamaguchi, Y., J. Chem. Phys., 2002, vol. 117, p. 9688.

    Article  CAS  Google Scholar 

  33. Tsuda, A. and Osuka, A., Adv. Mater., 2002, vol. 14, p. 75.

    Article  CAS  Google Scholar 

  34. Vorotyntsev, M.A. and Konev, D.V., Electrochim. Acta, 2011, vol. 56, p. 9105.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    D. V. Konev & M. A. Vorotyntsev

  2. Mendeleev Institute of Chemical Technology of Russia, Moscow, Russia

    D. V. Konev, D. K. Khairullina & M. A. Vorotyntsev

  3. Moscow State University, Moscow, Russia

    K. V. Lizgina, M. A. Shamraeva & M. A. Vorotyntsev

  4. Institut de Chimie Moléculaire, Université de Bourgogne et Franche-Comté, Dijon, France

    C. H. Devillers & M. A. Vorotyntsev

Authors
  1. D. V. Konev
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  2. K. V. Lizgina
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  3. D. K. Khairullina
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  4. M. A. Shamraeva
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  5. C. H. Devillers
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  6. M. A. Vorotyntsev
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Corresponding authors

Correspondence to D. V. Konev or K. V. Lizgina.

Additional information

Original Russian Text © D.V. Konev, K.V. Lizgina, D.K. Khairullina, M.A. Shamraeva, C.H. Devillers, M.A. Vorotyntsev, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 8, pp. 869–879.

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Konev, D.V., Lizgina, K.V., Khairullina, D.K. et al. Preparation of cobalt polyporphine and its catalytic properties in oxygen electroreduction. Russ J Electrochem 52, 778–787 (2016). https://doi.org/10.1134/S1023193516060069

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  • DOI: https://doi.org/10.1134/S1023193516060069

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