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Cyclic voltammetry studies of silicon–aluminum thin-film electrodes synthesized in the presence of oxygen

Abstract

The electrochemical characteristics of composite thin-film coatings prepared by sequential magnetron sputtering of thin layers of aluminum and silicon in an atmosphere with an oxygen addition were studied by cyclic voltammetry. The cyclic voltammograms on these composite samples did not differ from the cyclic volitammograms on pure silicon. The effective diffusion coefficient of lithium in the aluminum–silicon–oxygen composite was evaluated (it was of the order of 10–10 cm2/s).

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Correspondence to T. L. Kulova.

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Original Russian Text © T.L. Kulova, A.M. Skundin, V.N. Andreev, D.Yu. Gryzlov, A.A. Mironenko, A.S. Rudyi, V.N. Gusev, V.V. Naumov, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 12, pp. 1298–1302.

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Kulova, T.L., Skundin, A.M., Andreev, V.N. et al. Cyclic voltammetry studies of silicon–aluminum thin-film electrodes synthesized in the presence of oxygen. Russ J Electrochem 51, 1157–1161 (2015). https://doi.org/10.1134/S1023193515120095

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Keywords

  • thin-film silicon
  • Si–O–Al composite
  • lithium diffusion coefficient