Russian Journal of Electrochemistry

, Volume 51, Issue 12, pp 1157–1161 | Cite as

Cyclic voltammetry studies of silicon–aluminum thin-film electrodes synthesized in the presence of oxygen

  • T. L. KulovaEmail author
  • A. M. Skundin
  • V. N. Andreev
  • D. Yu. Gryzlov
  • A. A. Mironenko
  • A. S. Rudyi
  • V. N. Gusev
  • V. V. Naumov


The electrochemical characteristics of composite thin-film coatings prepared by sequential magnetron sputtering of thin layers of aluminum and silicon in an atmosphere with an oxygen addition were studied by cyclic voltammetry. The cyclic voltammograms on these composite samples did not differ from the cyclic volitammograms on pure silicon. The effective diffusion coefficient of lithium in the aluminum–silicon–oxygen composite was evaluated (it was of the order of 10–10 cm2/s).


thin-film silicon Si–O–Al composite lithium diffusion coefficient 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Kulova, T.L., Skundin, A.M., Andreev, V.N., Gryzlov, D.Yu., Mironenko, A.A., Rudyi, A.S., Gusev, V.N., and Naumov, V.V., Elektrokhim. Energ., 2013, vol. 13, p. 136.Google Scholar
  2. 2.
    Khansen, M. and Anderko, K., Struktury dvoinykh splavov: Sprav. (Structures of Binary Alloys: Handbook), Moscow: Metallurgizdat, 1962.Google Scholar
  3. 3.
    Shank, F., Struktury dvoinykh splavov: Sprav. (Structures of Binary Alloys: Handbook), Moscow: Metallurgiya, 1973.Google Scholar
  4. 4.
    Luais, E., Sakai, J., Desplobain, S., Gautier, G., Tran Van, F., and Ghamouss, F., J. Power Sources, 2013, vol. 242, p. 166.CrossRefGoogle Scholar
  5. 5.
    Ohara, Sh., Suzuki, J., Sekine, K., and Takamura, T., J. Power Sources, 2003, vols. 119–121, p. 591.CrossRefGoogle Scholar
  6. 6.
    Green, M., Fielder, E., Scrosati, B., Wachtler, M., and Moreno, J.S., Electrochem. Solid-State Lett., 2003, vol. 6, p. A75.Google Scholar
  7. 7.
    Yoshimura, K., Suzuki, J., Sekine, K., and Takamura, T., J. Power Sources, 2005, vol. 146, p. 445.CrossRefGoogle Scholar
  8. 8.
    Kulova, T.L., Skundin, A.M., Pleskov, Yu.V., Terukov, E.I., and Kon’kov, O.I., Russ. J. Electrochem., 2006, vol. 42, p. 363.CrossRefGoogle Scholar
  9. 9.
    Kulova, T.L., Skundin, A.M., Pleskov, Yu.V., Terukov, E.I., and Kon’kov, O.I., J. Electroanal. Chem., 2007, vol. 600, p. 21.CrossRefGoogle Scholar
  10. 10.
    Baranchugov, V., Markevich, E., Pollak, E., Salitra, G., and Aurbach, D., Electrochem. Commun., 2007, vol. 9, p. 796.CrossRefGoogle Scholar
  11. 11.
    Cao Cuong Nguyen and Seung-Wan Song, Electrochim. Acta, 2010, vol. 55, p. 3026.CrossRefGoogle Scholar
  12. 12.
    Zhongsheng Wen, Dong Lu, Junpeng Lei, Yingqing Fu, Liang Wang, and Juncai Sun, J. Electrochem. Soc., 2011, vol. 158, p. A809.Google Scholar
  13. 13.
    Bup Ju Jeon and Joong Kee Lee, Electrochim. Acta, 2011, vol. 56, p. 6261.CrossRefGoogle Scholar
  14. 14.
    Huixin Chen, Ying Xiao, Lin Wang, and Yong Yang, J. Power Sources, 2011, vol. 196, p. 6657.CrossRefGoogle Scholar
  15. 15.
    Hamon, Y., Brousse, T., Jousse, F., Topart, P., Buvat, P., and Schleich, D.M., J. Power Sources, 2001, vols. 97–98, p. 185.CrossRefGoogle Scholar
  16. 16.
    Chen, L.B., Xie, J.Y., Yu, H.C., and Wang, T.H., Electrochim. Acta, 2008, vol. 53, p. 8149.CrossRefGoogle Scholar
  17. 17.
    Sharma, R.A. and Seefurth, R.N., J. Electrochem. Soc., 1976, vol. 123, p. 1763.CrossRefGoogle Scholar
  18. 18.
    Nesper, R. and von Schnering, H.G., J. Solid State Chem., 1987, vol. 70, p. 48.CrossRefGoogle Scholar
  19. 19.
    Wen, C.J. and Huggins, R.A., J. Solid State Chem., 1981, vol. 37, p. 271.CrossRefGoogle Scholar
  20. 20.
    Weydanz, W.J., Wohlfahrt-Mehrens, M., and Huggins, R.A., J. Power Sources, 1999, vols. 81–82, p. 237.CrossRefGoogle Scholar
  21. 21.
    Limthongkul, P., Young-Il Jang, Dudney, N.J., and Yet-Ming Chiang, J. Power Sources, 2003, vols. 119–121, p. 604.CrossRefGoogle Scholar
  22. 22.
    Churikov, A.V., Ivanishchev, A.V., Ivanishcheva, I.A., Zapsis, K.V., Gamayunova, I.M., and Sycheva, V.O., Russ. J. Electrochem., 2008, vol. 44, p. 530.CrossRefGoogle Scholar
  23. 23.
    Yoshimura, K., Suzuki, Ju., Sekine, K., and Takamura, T., J. Power Sources, 2007, vol. 174, p. 653.CrossRefGoogle Scholar
  24. 24.
    Ding, N., Xu, J., Yao, Y.X., Wegner, G., Fang, X., Chen, Ch., and Lieberwirth, I., Solid State Ionics, 2009, vol. 180, p. 222.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • T. L. Kulova
    • 1
    Email author
  • A. M. Skundin
    • 1
  • V. N. Andreev
    • 1
  • D. Yu. Gryzlov
    • 1
  • A. A. Mironenko
    • 2
  • A. S. Rudyi
    • 2
  • V. N. Gusev
    • 2
  • V. V. Naumov
    • 2
  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia
  2. 2.Yaroslavl State UniversityYaroslavlRussia

Personalised recommendations