Skip to main content
Log in

In situ carbon-coated LiCoPO4 synthesized via a microwave-assisted path

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

A very fast and efficient synthesis approach was used for the preparation of in situ carbon-coated LiCoPO4 particles which are used as active materials for the preparation of electrodes for lithium-ion batteries. The synthesis approach is based on a microwave-assisted synthesis. The prepared lithium-ion batteries exhibited a very high initial specific charge of about 161 A h kg−1 at 1 C and an excellent low fading of about 17% after 1700 cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Brinkmann, K. and Marderwald, E., ETZ-A, 1960, vol. 73, p. 449.

    Google Scholar 

  2. Spencer, P.L., Application, U.P., USA, 1950.

    Google Scholar 

  3. Schmink, J.R., Holcomb, J.L., and Leadbeater, N.E., Org. Lett., 2009, vol. 11, pp. 365–368.

    Article  CAS  Google Scholar 

  4. Leadbeater, N.E. and Schmink, J.R., Nat. Protoc., 2008, vol. 3, pp. 1–7.

    Article  CAS  Google Scholar 

  5. Bilecka, I., Djerdj, I., and Niederberger, M., Chem. Commun., 2008, Issue 7, pp. 886–888.

    Google Scholar 

  6. Wolfenstine, J., Read, J., and Allen, J.L., J. Power Sources, 2007, vol. 163, pp. 1070–1073.

    Article  CAS  Google Scholar 

  7. Allen, J.L., Jow, T.R., and Wolfenstine, J., Chem. Mater., 2007, vol. 19, pp. 2108–2111.

    Article  CAS  Google Scholar 

  8. Padhi, A.K., Nanjundaswamy, K.S., and Goodenough, J.B., J. Electrochem. Soc., 1997, vol. 144, pp. 1188–1194.

    Article  CAS  Google Scholar 

  9. Sharabi, R., Markevich, E., Fridman, K., Gershinsky, G., Salitra, G., Aurbach, D., Semrau, G., Schmidt, M.A., Schall, N., and Bruenig, C., Electrochem. Commun., 2013, vol. 28, pp. 20–23.

    Article  CAS  Google Scholar 

  10. Rogers, R.E., Clarke, G.M., Matthew, O.N., Ganter, M.J., DiLeo, R.A., Staub, J.W., Forney, M.W., and Landi, B.J., J. Appl. Electrochem., 2013, vol. 43, pp. 271–278.

    Article  CAS  Google Scholar 

  11. Jaehne, C., Neef, C., Koo, C., Meyer, H.-P., and Klingeler, R., J. Mater. Chem., Ser. A, 2013, vol. 1, pp. 2856–2862.

    Article  CAS  Google Scholar 

  12. Dimesso, L., Spanheimer, C., Jaegermann, W., Zhang, Y., and Yarin, A.L., Electrochim. Acta, 2013, vol. 95, pp. 38–42.

    Article  CAS  Google Scholar 

  13. Wang, S.-L., Tang, Z.-Y., Sha, O., and Yan, J., Acta Phys.-Chim. Sinica, 2012, vol. 28, pp. 343–348.

    Google Scholar 

  14. Prabu, M., Selvasekarapandian, S., Reddy, M.V., and Chowdari, B.V.R., J. Solid State Electrochem., 2012, vol. 16, pp. 1833–1839.

    Article  CAS  Google Scholar 

  15. Dimesso, L., Cherkashinin, G., Spanheimer, C., and Jaegermann, W., J. Alloys Compounds, 2012, vol. 516, pp. 119–125.

    Article  CAS  Google Scholar 

  16. Devaraju, M.K., Rangappa, D., and Honma, I., Electrochim. Acta, 2012, vol. 85, pp. 548–553.

    Article  CAS  Google Scholar 

  17. Aravindan, V., Cheah, Y.L., Ling, W.C., and Madhavi, S., J. Electrochem. Soc., 2012, vol. 159, pp. A1435–A1439.

    Article  CAS  Google Scholar 

  18. Allen, J.L., Jow, T.R., and Wolfenstine, J., in Intercalation Compounds for Rechargeable Batteries, vol. 41, Julien, C.M., Meng, S., Zaghib, K., and Kanno, R., Ed., 2012, pp. 15–20.

  19. Markevich, E., Sharabi, R., Haik, O., Borgel, V., Salitra, G., Aurbach, D., Semrau, G., Schmidt, M.A., Schall, N., and Stinner, C., J. Power Sources, 2011, vol. 196, pp. 6433–6439.

    Article  CAS  Google Scholar 

  20. Kishore, M. and Varadaraju, U.V., Mater. Res. Bull., 2005, vol. 40, pp. 1705–1712.

    Article  CAS  Google Scholar 

  21. Jahne, C., Neef, C., Koo, C., Meyer, H.-P., and Klingeler, R., J. Mater. Chem., Ser. A, 2013, vol. 1, pp. 2856–2862.

    Article  Google Scholar 

  22. Bramnik, N.N., Bramnik, K.G., Buhrmester, T., Baehtz, C., Ehrenberg, H., and Fuess, H., J. Solid State Electrochem., 2004, vol. 8, pp. 558–564.

    CAS  Google Scholar 

  23. Eftekhari, A., J. Electrochem. Soc., 2004, vol. 151, pp. A1816–A1819.

    Article  CAS  Google Scholar 

  24. Eftekhari, A., J. Electrochem. Soc., 2004, vol. 151, pp. A1456–A1460.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Andreas Hintennach.

Additional information

Published in Russian in Elektrokhimiya, 2015, Vol. 51, No. 4, pp. 358–362.

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rosenberg, S., Hintennach, A. In situ carbon-coated LiCoPO4 synthesized via a microwave-assisted path. Russ J Electrochem 51, 305–309 (2015). https://doi.org/10.1134/S1023193515040102

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193515040102

Keywords

Navigation