Abstract
The operational impedance technique in two modes (chronoamperometric and chronopotentiometric) was used to study the kinetics of the charging process of the blocked (inert) electrode/solid electrolyte interface in the case of small and large charging times. The case of slow diffusion and adsorption-desorption of a given species type, i.e., rigid lattice defects in solid electrolyte (minor charge carriers), is analyzed. It is shown that in the chronopotentiometric mode, analytical current-time relationships differ at small charging times and at large charging times. It is found in the chronoamperometric mode that formation of a double electric layer at the blocked electrode/solid electrolyte interface occurs much faster at large times than at small times.
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Original Russian Text © R.M. Guseinov, R.A. Radzhabov, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 4, pp. 371–377.
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Guseinov, R.M., Radzhabov, R.A. Blocked (inert) electrode/solid electrolyte interface in chronoamperometric and chronopotentiometric charging modes. Russ J Electrochem 51, 318–324 (2015). https://doi.org/10.1134/S1023193515040059
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DOI: https://doi.org/10.1134/S1023193515040059