Abstract
The mechanism and kinetics of electrochemical formation of anodic oxide films on iron-triad metal monosilicides in the 0.5 M H2SO4 solution in the potential range of 0.5 to 1.5 V (NHE) were studied by the methods of polarization and impedance measurements. It was concluded that the oxide films on the surface of studied silicides consisted predominantly of SiO2 and exhibited high barrier properties. The oxide film thickness and specific resistance in relation to the electrode potential were calculated from the impedance data. The constants of oxide film growth were determined.
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Odynets, L.L. and Orlov, V.M., Anodnye oksidnye plenki (Anodic Oxide Films), Leningrad: Nauka, 1990.
Mukhurov, N.I., Mikroelektronika, 1999, vol. 28, p. 75.
Mileshko, L.P., Electron. Promyshl., 2004, no. 4, p. 160.
Ramirez, A.P., Science, 2007, vol. 315, p. 1377.
Park, S.S., Eom, S.M., Dong, H., Seo, D.H., and Shul, I.G., Res. Chem. Intermed., 2010, vol. 36, p. 77.
Anokhin, V.Z., Goncharov, E.G., Kostryukova, E.P., Pshestanchik, V.R., and Marshakova, T.A., Praktikum po khimii i tekhnologii poluprovodnikov: Ucheb. pos. dlya studentov vuzov (Practical Course of Chemistry and Technology of Semiconductors: Textbook for Students), Moscow: Vyssh. Shk, 1978.
Ivanchenko, M.V., Gritsenko, V.A., Nepomnyashchii, A.V., and Saranin, A.A., Zh. Tekh. Fiz., 2012, vol. 82, no. 5, p. 115.
Nikiforova-Denisova, S.N. and Lyubushkin, E.N., Termicheskie protsessy (Thermal Processes), Moscow: Vyssh. Shk, 1989.
Shein, A.B., Elektrokhimiya silitsidov i germanidov perekhodnykh metallov (Electrochemistry of Silicides and Germanides of Transient Metals), Perm: Perm. Gos. Univ., 2009.
Panteleeva, V.V. and Shein, A.B., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2012, vol. 55, no. 7, p. 35.
Kichigin, V.I. and Shein, A.B., Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2011, vol. 47, p. 218.
Tyurin, A.G., Mosunova, T.V., and Nikolaichuk, P.A., Vestn. Yuzhno-Ural. Gos. Univ., Ser. Khim., 2010, no. 11, p. 52.
Shein, A.B. and Zubova, E.N., Russ. J. Electrochem., 2004, vol. 40, p. 222.
Panteleeva, V.V. and Shein, A.B., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2013, vol. 56, no. 10, p. 48.
Latimer, W.M., The Oxidation States of the Elements and Their Potentials in Aqueous Solutions, New York, Prentice-Hall, 1952.
Armstrong, R.D. and Edmondson, K., Electrochim. Acta, 1973, vol. 18, p. 937.
Barsoukov, E. and Macdonald, J.R., Impedance Spectroscopy: Theory, Experiment and Applications, Hoboken, New Jersey: Wiley, 2005.
Azumi, K., Ohtsuka, T., and Sato, N., Trans. Japan Inst. Metals, 1986, vol. 27, p. 382.
Lasia, A., Electrochemical impedance spectroscopy and its applications, in Modern Aspects of Electrochemistry, Conway, B.E., Bockris, J., and White, R., Eds., New York: Kluwer Academic/Plenum Publishers, 1999, vol. 32, p. 143.
Orazem, M.E. and Tribollet, B., Electrochemical Impedance Spectroscopy, Hoboken, New York: Wiley and Sons, 2008.
Gassa, L.M., Castro Luna, A.M., Torres Sanchez, R.M., and Zerbino, J.O., Portugal. Electrochim. Acta, 2004, vol. 22, p. 81.
Schiller, C. and Strunz, W., Electrochim. Acta, 2001, vol. 46, p. 3619.
Lazarev, V.B., Krasov, V.G., and Shaplygin, I.S., Elektroprovodnost’ okisnykh sistem i plenochnykh struktur (Conductivity of Oxide Systems and Film Structures), Moscow: Nauka, 1978.
Spravochnik po elektrokhimii (Handbook of Electrochemistry), Sukhotin, A.M., Ed., Leningrad: Khimiya, 1981.
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Original Russian Text © V.V. Panteleeva, A.B. Shein, 2014, published in Elektrokhimiya, 2014, Vol. 50, No. 11, pp. 1152–1159.
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Panteleeva, V.V., Shein, A.B. Growth of anodic oxide films on iron-triad metal monosilicides in sulfuric acid electrolyte. Russ J Electrochem 50, 1036–1043 (2014). https://doi.org/10.1134/S102319351411007X
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DOI: https://doi.org/10.1134/S102319351411007X