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Electropolymerization of N,N-dimethylaniline in presence of sodium dodecyl sulfate and its electrochemical properties

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Abstract

Poly(N,N-dimethylaniline) (PDMA) was formed by successive cyclic voltammetry in monomer solution in the presence of sodium dodecyl sulfate (SDS) on the surface of a carbon paste electrode. The polymerization behavior of N,N-dimethylaniline in the presence of SDS is quite different from that of N,N-dimethylaniline in the absence of SDS. The effect of varying amount of SDS on the rate of polymerization of N,N-dimethylaniline was investigated. The electrochemical behavior of the SDS-PDMA carbon paste electrode has been investigated by cyclic voltammetry in 0.5 M H2SO4 and 5 mM K4[Fe(CN)6]/0.1 M KCl solutions as the supporting electrolyte and model system, respectively. The synthesized PDMA was characterized by FT-IR and scanning electron microscopy (SEM). Ni(II) ions were incorporated into the electrode by immersion of the polymeric modified electrode having amine groups in 0.1 M Ni(II) ion solution. The electro catalytic oxidations of methanol at the surface of the Ni/SDS-PDMA electrode were studied in a 0.1 M NaOH solution. Compared to bare carbon paste and PDMA-modified carbon paste electrodes; the SDS-PDMA electrode significantly enhanced the catalytic efficiency of Ni ions for methanol oxidation.

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References

  1. Diaz, A.F., Kanazawa, K.K., and Gardini, G.P., J. Chem. Soc. Chem. Commim., 1979, p. 635.

    Google Scholar 

  2. Wplin, J. and Dudek, L.P., J. Polym. Sci. Polym. Chem. Ed., 1980, 18, 2869.

    Article  Google Scholar 

  3. Tourillon, G. and Gamier, F., J. Electrochem. Soc. 1983, vol. 130, p. 2042.

    Article  CAS  Google Scholar 

  4. Surville, R.D., Jozegowicz, M., and Yu, L.T., Electrochim. Acta, 1968, vol. 13, p. 1451.

    Article  Google Scholar 

  5. Volkov, A., Tourillon, G., and Lacaze, P.C., J. Electroanal Chem., 1980, vol. 115, p. 279.

    Article  CAS  Google Scholar 

  6. Frommer, J.E., 188th American Chemical Society Meeting, Philadelphia, 1984.

    Google Scholar 

  7. Shenlong, W., Fosong, W., and Xiaohui, G., Synth. Methods, 1986, vol. 16, p. 99.

    Article  Google Scholar 

  8. Cattarin, S., Doubova, L., and Mengoli, G., Electrochim. Acta, 1988, vol. 33, p. 1077.

    Article  CAS  Google Scholar 

  9. Chiba, K., Ohsaka, T., and Oyama, N., J. Electroanal. Chem., 1987, vol. 217, p. 239.

    Article  CAS  Google Scholar 

  10. Hayat, U., Bartlett, P.N., and Dodd, G.H., J. Electroanal. Chem., 1987, vol. 220, p. 287.

    Article  CAS  Google Scholar 

  11. Mizoguchi, T. and Adams, R.N., J. Am. Chem. Soc., 1962, vol. 84, p. 2058.

    Article  CAS  Google Scholar 

  12. Kitani, A., Yano, J., and Sasaki, K., Chem. Lett., 1984, p. 1565.

    Google Scholar 

  13. Oyama, N., Ohsaka, T., and Shimizu, T., Anal Chem., 1985, vol. 57, p. 1526.

    Article  CAS  Google Scholar 

  14. Ohsaka, T., Okajima, T., and Oyama, N., J. Electroanal. Chem., 1986, vol. 215, p. 191.

    Article  CAS  Google Scholar 

  15. Ohsaka, T., Okajima, T., and Oyama, N., J. Electroanal. Chem., 1986, vol. 200, p. 159.

    Article  CAS  Google Scholar 

  16. Roy, P.R., Okajima, T., and Ohsaka, T., Bioelectrochem., 2003, vol. 59, p. 11.

    Article  CAS  Google Scholar 

  17. Malinauskas, A. and Holze, R., Electrochim. Acta, 1999, vol. 44, p. 2613.

    Article  CAS  Google Scholar 

  18. Appleby, A.J. and Foulkess, F.R., Fuel Cell Handbook, New York: Van Nostrand Reinhold, 1989, ch. 11.

    Google Scholar 

  19. Wasmus, S. and Kuver, A., J. Electroanal. Chem., 1999, vol. 461, p. 14.

    Article  CAS  Google Scholar 

  20. Ren, X., Zelenay, P., and Thomas, S., J. Power Sources, 2000, vol. 86, p. 111.

    Article  CAS  Google Scholar 

  21. Wei, Z., Guo, H., and Tang, Z., J. Power Sources, 1996, vol. 58, p. 239.

    Article  CAS  Google Scholar 

  22. Lamy, C., Lima, A., and Rhun, V.L., J. Power Sources, 2002, vol. 105, p. 283.

    Article  CAS  Google Scholar 

  23. Kulesza, P.J., Matczak, M., and Wolkiewicz, A., Electrochim. Acta, 1999, vol. 44, p. 2131.

    Article  CAS  Google Scholar 

  24. Castro Luna, A.M., J. Appl. Electrochem., 2000, vol. 30, p. 1137.

    Article  Google Scholar 

  25. Mikhaylova, A.A., Khazova, O.A., and Bagotzky, V.S., J. Electroanal. Chem., 2000, vol. 480, p. 225.

    Article  CAS  Google Scholar 

  26. Delime, F., Leger, J.M., and Lamy, C., J. Appl. Electrochem., 1999, vol. 29, p. 1249.

    Article  CAS  Google Scholar 

  27. Venancio, E.C., Nappom, W.T., and Motheo, A.J., Electrochim. Acta, 2002, vol. 47, p. 1495.

    Article  CAS  Google Scholar 

  28. Golabi, S.M. and Nozad, A., Electroanalysis, 2004, vol. 16, p. 199.

    Article  CAS  Google Scholar 

  29. Liu, S.J., Electrochim. Acta, 2004, vol. 49, p. 3235.

    Article  CAS  Google Scholar 

  30. Perez-Morales, M., Munoz, E., and Martin-Romero, M.T., Langmuir, 2005, vol. 21, p. 5468.

    Article  CAS  Google Scholar 

  31. Lapin, E., Jureviciute, I., and Mazeikiene, R., Synt. Met., 2010, vol. 160, p. 1843.

    Article  CAS  Google Scholar 

  32. Bard, A.J. and Faulkner, L.R., Electrochemical Methods, New York: John Wiley and Sons, 2001.

    Google Scholar 

  33. Bereket, G. and Duran, B., Prog. Org. Coat., 2009, vol. 64, p. 57.

    Article  CAS  Google Scholar 

  34. Liu, X.X., Zhang, L., and Li, Y.B., Mat. Sci., 2005, vol. 40, p. 4511.

    Article  CAS  Google Scholar 

  35. Wei, D., Kvarnstrom, C., and Lindfors, T., Synt. Met., 2006, vol. 156, p. 541.

    Article  CAS  Google Scholar 

  36. Eramo, F.D., Marioli, J.M., and Arevalo, A.A., Electroanalysis, 1999, vol. 11, p. 481.

    Article  Google Scholar 

  37. Casella, I.G., Cataldi, T.R.I., and Guerrieri, A., Anal. Chim. Acta, 1996, vol. 335, p. 217.

    Article  CAS  Google Scholar 

  38. Ojani, R., Raoof, J.B., and Fathi, Sh., J. Solid State Electrochem., 2009, vol. 13, p. 927.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Islamic Azad University, Science and Research Ayatollah Amoli Branch, Amol, Iran

    Shahla Fathi & Mohamad Reza Mahdavi

Authors
  1. Shahla Fathi
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  2. Mohamad Reza Mahdavi
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Correspondence to Shahla Fathi.

Additional information

Published in Russian in Elektrokhimiya, 2014, Vol. 50, No. 11, pp. 1198–1206.

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Fathi, S., Mahdavi, M.R. Electropolymerization of N,N-dimethylaniline in presence of sodium dodecyl sulfate and its electrochemical properties. Russ J Electrochem 50, 1077–1084 (2014). https://doi.org/10.1134/S1023193514090031

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  • DOI: https://doi.org/10.1134/S1023193514090031

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