Abstract
The data obtained by impedance spectroscopy (1 Hz to 32 MHz) and broad-band dielectric spectroscopy (30 GHz-150 THz) are presented for crystals based on zirconia doped by 1.5–30 mol % Y2O3 or 10 mol % Sc2O3 and 1 mol % Y2O3. The maximum of ionic conductivity is confirmed for the latter composition in the working temperature range of solid oxide fuel cells where the doping by scandium and yttrium oxides makes it possible to obtain isotropic single crystals. Dependences of dielectric permeability and high-frequency conductivity of materials on the composition of crystals and temperature are presented.
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References
Applications of Solid Electrolytes, Takahashi, T. and Kozawa, A., Eds., Cleveland: JEC Press, 1980.
Zhuiykov, S., Electrochemistry of Zirconia Gas Sensors, Boca Raton, FL: CRC Press, 2007.
Solid State Electrochemistry I: Fundamentals, Materials and Their Applications, Kharton, V.V., Ed., Weinheim: Wiley-VC, 2009.
Kharton, V.V., Naumovich, E.N., and Vecher, A.A., J. Solid State Electrochem., 1999, vol. 3, p. 61.
Kharton, V.V., Marques, F.M.B., and Atkinson, A., Solid State Ionics, 2004, vol. 174, p. 135.
Preis, W., Waldhaeusl, J., Egger, A., Sitte, W., De Carvalho, E., and Irvine, J.T.S., Solid State Ionics, 2011, vol. 192, p. 148.
Spirin, A., Ivanov, V., Nikonov, A., Lipilin, A., Paranin, S., Khrustov, V., and Spirina, A., Solid State Ionics, 2012, vol. 225, p. 448.
Chen, Y., Orlovskaya, N., Klimov, M., Huang, X., Cullen, D., Graule, T., and Kuebler, J., Fuel Cells, 2012, vol. 12, p. 722.
Hartmanova, M., Kundracik, F., Navratil, V., Schulz, H., and Lomonova, E.E., Solid State Ionics, 2000, vol. 136–137, p. 107.
Pimenov, A., Ullrich, J., Lunkenheimer, P., Loidl, A., and Ruscher, C.H., Solid State Ionics, 1998, vol. 109, p. 111.
Borik, M.A., Lomonova, E.E., Osiko, V.V., Panov, V.A., Porodinkov, O.E., Vishnyakova, M.A., Voron’ko, Yu.K., and Voronov, V.V., J. Cryst.Growth, 2005, vol. 275, p. e2173.
Aleksandrov, V.I., Osiko, V.V., Prokhorov, A.M., and Tatarintsev, V.M., Russ. Chem. Rev., 1978, vol. 47, no. 3, p. 213.
Kozlov, G. and Volkov, A., Millimeter and Submillimeter Wave Spectroscopy of Solids, Berlin: Springer, 1998, vol. 74, pp. 51–110.
Volkov, A.A. and Prokhorov, A.S., Izv. Vyssh. Uchebn. Zaved., Radiofiz., 2003, vol. 46, no. 8–9, p. 732.
Fleig, J. and Maier, J., J. Eur. Ceram. Soc., 1999, vol. 19, p. 693.
Chen, B., Hallstedt, L.J., and Gauckler, L.J., Solid State Ionics, 2004, vol. 170, p. 255.
Sternik, M. and Parlinski, K., J. Chem. Phys., 2005, vol. 122, p. 064707.
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Original Russian Text © V.G. Artemov, I.E. Kuritsyna, S.P. Lebedev, G.A. Komandin, P.O. Kapralov, I.E. Spektor, V.V. Kharton, S.I. Bredikhin, A.A. Volkov, 2014, published in Elektrokhimiya, 2014, Vol. 50, No. 7, pp. 768–772.
This publication was prepared based on a lecture delivered at the All-Russian Conference with international participation “Fuel Cells and Power Plants,” Chernogolovka, 2013.
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Artemov, V.G., Kuritsyna, I.E., Lebedev, S.P. et al. Analysis of electric properties of ZrO2-Y2O3 single crystals using teraherz IR and impedance spectroscopy techniques. Russ J Electrochem 50, 690–693 (2014). https://doi.org/10.1134/S1023193514070039
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DOI: https://doi.org/10.1134/S1023193514070039