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Silicon-containing anodes with high capacity loading for lithium-ion batteries

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Abstract

Comparative analysis of cycling performance of hybrid electrodes based on the MAG synthetic graphite mechanic mixtures with silicon nanopowder and “nano-Si/SiO2/hard carbon” ceramic frame-ordered composite in 1 M LiPF6 solution in a monofluoroethylene carbonate-ethyl methyl carbonate mixture (30: 70, v/v), added with 3 wt % vinylene carbonate and 2 wt % ethylene sulfite, is performed. The high capacity loading (up to 6.8 mA h cm−2 at the electrode layer thickness of 37 μm) and acceptable accumulated irreversible capacity of the composite-containing electrodes are achieved, due to the electrodes’ high density and stable silicon-containing electrode/electrolyte interface formation.

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Authors and Affiliations

  1. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, ul. Generala Naumova 17, Kiev, 03164, Ukraine

    S. P. Kuksenko

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  1. S. P. Kuksenko
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Correspondence to S. P. Kuksenko.

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Original Russian Text © S.P. Kuksenko, 2014, published in Elektrokhimiya, 2014, Vol. 50, No. 6, pp. 599–610.

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Kuksenko, S.P. Silicon-containing anodes with high capacity loading for lithium-ion batteries. Russ J Electrochem 50, 537–547 (2014). https://doi.org/10.1134/S1023193514060068

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  • DOI: https://doi.org/10.1134/S1023193514060068

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