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Electrochemiluminescence at nitrogen doped diamond-like carbon film electrodes

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Abstract

In the given paper the results of investigation of nitrogen doped diamond-like carbon films (DLF) for the fabrication of electrodes of electrochemical and electrochemiluminescent (ECL) cells are presented. The surface nanomorphology of modified electrodes was studied using the atomic-force microscopy method. The mechanisms of ECL reactions with Ru(bpy) 1+3 /Ru(bpy) 3+3 (recombination Ru(bpy) 3+3 /OH− (ECL without co-reactant) and Ru(bpy) 3+3 /tripropylamine (ECL with co-reactant) were studied on DLF modified electrodes in the aqueous solution. The work shows advantages of DLF as an electrode material for further analytical applications.

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Authors and Affiliations

  1. Laboratory of Analytical Optochemotronics, Kharkov National University of Radio Electronics, 14 Lenin ave., 61166, Kharkiv, Ukraine

    D. V. Snizhko, Yu. T. Zholudov, O. M. Bilash, A. V. Kukoba & M. M. Rozhitskii

Authors
  1. D. V. Snizhko
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  2. Yu. T. Zholudov
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  3. O. M. Bilash
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  4. A. V. Kukoba
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  5. M. M. Rozhitskii
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Correspondence to D. V. Snizhko.

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Publishedin Russian in Elektrokhimiya, 2014, Vol. 50, No. 3, pp. 292–298.

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Snizhko, D.V., Zholudov, Y.T., Bilash, O.M. et al. Electrochemiluminescence at nitrogen doped diamond-like carbon film electrodes. Russ J Electrochem 50, 260–266 (2014). https://doi.org/10.1134/S1023193514020037

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  • DOI: https://doi.org/10.1134/S1023193514020037

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