Skip to main content
SpringerLink
Log in

Fabrication of highly sensitive cysteine electrochemical sensor based on nanostructured compound and carbon nanotube modified electrode

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

This work describes the electrochemical behavior of copper(II)-bis[5-((4-n-decyloxyphenyl)azo)-N-(nethanol)-salicylaldiminato]film immobilized on the surface of multiwall carbon nanotube glassy carbon electrode and its electrocatalytic activity toward the oxidation of L-cysteine. The surface structure and composition of the sensor was characterized by scanning electron microscopy. Electrocatalytic oxidation of L-cysteine on the surface of modified electrode was investigated with cyclic voltammetry, chronoamperometry and hydrodynamic amperometery methods and the results showed that the Cu-Schiff base film displays excellent electrochemical catalytic activities towards L-cysteine oxidation. The modified electrode indicated reproducible behavior and high level of stability during the electrochemical experiments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Chen, H.L. and Li, M.S., Structure and Function of Biomacromoleculles, Shanghai: Shanghai Science Press, 1999, p. 4.

    Google Scholar 

  2. Kulys, J. and Drungiliene, A., Anal. Chim. Acta, 1991, vol. 243, p. 287.

    Article  CAS  Google Scholar 

  3. Townshend, A., Encyclopedia of Analytical Science, London: Academic Press, 1995, vol. 6, p. 3319.

    Google Scholar 

  4. Filanovsky, B., Anal. Chim. Acta, 1999, vol. 394, p. 91.

    Article  CAS  Google Scholar 

  5. Droge, W., Eck, H.P., and Mihm, S., Immunol. Today, 1992, vol. 13, p. 211.

    Article  CAS  Google Scholar 

  6. Shahrokhian, S., Anal. Chem., 2001, vol. 73, p. 5972.

    Article  CAS  Google Scholar 

  7. Wang, W.H., Rusin, O., Xu, X.Y., Kim, K.K., Escobedo, J.O., Fakayode, S.O., Fletcher, K.A., Lowry, M., Schowalter, C.M., Lawrence, C.M., Fronczek, F.R., Warner, I.M., and Strongin, R.M., J. Am. Chem. Soc., 2005, vol. 127, p. 15949.

    Article  CAS  Google Scholar 

  8. Cooper, A.J.L., Annu. Rev. Biochem., 1983, vol. 52, p. 187.

    Article  CAS  Google Scholar 

  9. Griffith, O.W., Methods Enzymol., 1987, vol. 143, p. 366.

    Article  CAS  Google Scholar 

  10. Chwatko, G. and Bald, E., Talanta, 2000, vol. 52, p. 509.

    Article  CAS  Google Scholar 

  11. Cavins, J.F., Krull, L.H., Friedman, M., Gibbs, D.E., and Inglett, G.E., J. Agric. Food Chem., 1972, vol. 20, p. 1124.

    Article  CAS  Google Scholar 

  12. Ogwu, V. and Cohen, G., Free Radic. Biol. Med., 1998, vol. 25, p. 362.

    Article  CAS  Google Scholar 

  13. Zaia, D.A.M., Ribas, K.C.L., and Zaia, C.T.B.V., Talanta, 1999, vol. 50, p. 1003.

    Article  CAS  Google Scholar 

  14. Nekrassova, O., Lawrence, N.S., and Compton, R.G., Talanta, 2003, vol. 60, p. 1085.

    Article  CAS  Google Scholar 

  15. Nekrassova, O., Lawrence, N.S., and Compton, R.G., Electroanalysis, 2004, vol. 16, p. 1285.

    Article  CAS  Google Scholar 

  16. Halbert, M.K. and Baldwin, R.P., Anal. Chem., 1985, vol. 57, p. 591.

    Article  CAS  Google Scholar 

  17. Wang, Z. and Pang, D., J. Electroanal. Chem., 1990, vol. 283, p. 349.

    Article  CAS  Google Scholar 

  18. Zhao, Y.D., Zhang, W.D., Chen, H., and Luo, Q.M., Sens. Actuat. B, 2003, vol. 92, p. 279.

    Article  CAS  Google Scholar 

  19. Salimi, A. and Pourbeyrum, S., Talanta, 2003, vol. 60, p. 205.

    Article  CAS  Google Scholar 

  20. Chen, S.M. and Chen, S.V., Electrochim. Acta, 2003, vol. 48, p. 513.

    Article  CAS  Google Scholar 

  21. Mimica, D., Bedioui, F., and Zagal, J.H., Electrochim. Acta, 2002, vol. 48, p. 323.

    Article  CAS  Google Scholar 

  22. Digga, A., Gracheva, S., Livingstone, C., and Davis, J., Electrochem. Commun., 2003, vol. 5, p. 732.

    Article  CAS  Google Scholar 

  23. Zen, J.-M., Kumar, A.S., and Chen, J.C., Anal. Chem., 2001, vol. 73, p. 1169.

    Article  CAS  Google Scholar 

  24. Inoue, T. and Kirchhoff, J.R., Anal. Chem., 2000, vol. 72, p. 5755.

    Article  CAS  Google Scholar 

  25. Shahrokhian, S. and Karimi, M., Electrochim. Acta, 2004, vol. 50, p. 77.

    Article  CAS  Google Scholar 

  26. Yakabson, B.I. and Smally, R.E., Am. Sci., 1997, vol. 85, p. 324.

    Google Scholar 

  27. Inagaki, M., Kaneko, K., and Nishizawa, T., Carbon, 2004, vol. 42, p. 1401.

    Article  CAS  Google Scholar 

  28. Gooding, J.J., Electrochim. Acta, 2005, vol. 50, p. 3049.

    Article  CAS  Google Scholar 

  29. Sherigara, B.S., Kutner, W., and Souza, F.D., Electroanalysis, 2003, vol. 15, p. 753.

    Article  CAS  Google Scholar 

  30. Gong, K., Yan, Y., Zhang, M., Su, L., Xiong, S., and Mao, L., Anal. Sci., 2005, vol. 21, p. 1383.

    Article  CAS  Google Scholar 

  31. Wang, J., Electroanalysis, 2005, vol. 17, p. 7.

    Article  CAS  Google Scholar 

  32. Azamian, B.R., Davis, J.J., Coleman, K.S., Bagshaw, C.B., and Green, M.L.H., J. Am. Chem. Soc., 2002, vol. 124, p. 12664.

    Article  CAS  Google Scholar 

  33. Wang, J., Hocevar, S.B., and Ogorevc, B., Electrochem. Commun., 2004, vol. 6, p. 176.

    Article  CAS  Google Scholar 

  34. Wang, J., Li, M., Shi, Z., Li, N., and Gu, Z., Anal. Chem., 2002, vol. 74, p. 1993.

    Article  CAS  Google Scholar 

  35. Wang, Z., Wang, Y., and Luo, G., Electroanalysis, 2003, vol. 15, p. 1129.

    Article  Google Scholar 

  36. Lawrence, N.S. and Wang, J., Electrochem. Commun., 2005, vol. 8, p. 71.

    Article  Google Scholar 

  37. Sun, D., Zhu, L., Huang, H., and Zhu, G., J. Electroanal. Chem., 2006, vol. 597, p. 39.

    Article  CAS  Google Scholar 

  38. Zhao, K., Song, H., Zhung, S., Dai, L., He, P., and Fang, Y., Electrochem. Commun., 2007, vol. 9, p. 65.

    Article  CAS  Google Scholar 

  39. Li, Z., Chen, J., Pan, D., Tao, W., Nie, L., and Yao, S., Electrochim. Acta, 2006, vol. 51, p. 4255.

    Article  CAS  Google Scholar 

  40. Czerw, R., Guo, Z., Ajayan, P.M., Sun, Y.P., and Carol, D.L., Nano Lett., 2001, vol. 1, p. 423.

    Article  CAS  Google Scholar 

  41. Bianco, A. and Prato, M., Adv. Mater., 2003, vol. 15, p. 1765.

    Article  CAS  Google Scholar 

  42. Frehill, F., Vos, J.G., Benrezzak, S., Koos, A.A., Konya, Z., Ruther, M.G., Blau, W.J., Fonseca, A., Nagy, J.B., Biro, L.P., Minett, A.I., and Panhuis, M., J. Am. Chem. Soc., 2002, vol. 124, p. 13694.

    Article  CAS  Google Scholar 

  43. Chen, R.J., Zhang, Y., Wang, D., and Dai, H., J. Am. Chem. Soc., 2001, vol. 123, p. 3838.

    Article  CAS  Google Scholar 

  44. Li, J., Yu, Q., and Peng, T., Anal. Sci., 2005, vol. 21, p. 377.

    Article  CAS  Google Scholar 

  45. Sun, X., Li, R., Villers, D., Dodelet, J.P., and Desilet, S., Chem. Phys. Lett., 2003, vol. 379, p. 99.

    Article  CAS  Google Scholar 

  46. Dai, X., Wildgoose, G.G., and Compton, R.G., Analyst, 2006, vol. 131, p. 901.

    Article  CAS  Google Scholar 

  47. Ozoemena, K.I., Nyokong, T., Nkosi, D., Chambrier, I., and Cook, M.J., Electrochim. Acta, 2007, vol. 52, p. 4132.

    Article  CAS  Google Scholar 

  48. Subramanian, V., Zhu, H., and Wei, B., Electrochem. Commun., 2006, vol. 8, p. 827.

    Article  CAS  Google Scholar 

  49. Nejati, K. and Rezvani, Z., New. J. Chem., 2003, vol. 27, p. 1665.

    Article  CAS  Google Scholar 

  50. Rezvani, Z., Divband, B., Abbasi, A.R., and Nejati, K., Polyhedron, 2006, vol. 25, p. 1915.

    Article  CAS  Google Scholar 

  51. Kissinger, P.T. and Heineman, W.R., Laboratory Techniques in Electroanalytical Chemistry, New York: Marcel Dekker, 1984, p. 152.

    Google Scholar 

  52. Antoniadou, S., Jannakoudakis, A.D., and Theodoridou, E., Synthetic Metals, 1980, vol. 30, p. 579.

    Google Scholar 

  53. Salimi, A., Korani, A., Hallaj, R., Khoshnavazi, R., and Hadadzadeh, H., Analytica. Chimica. Acta, 2009, vol. 635, p. 63.

    Article  CAS  Google Scholar 

  54. Otero, T.F. and Larreta-Azelain, E.D., Polymer, 1988, vol. 29, p. 1522.

    Article  CAS  Google Scholar 

  55. Murray, R.W. and Bard, A.J., Electroanalytical Chemistry, New York: Marcel Dekker, 1984, p. 191.

    Google Scholar 

  56. Bard, A.J. and Faulkner, L.R., Electrochemical Methods-Fundamentals and Application, New York: John Wiley and Sons, 2000, p. 251.

    Google Scholar 

  57. Pariente, F., Lorenzo, E., Tobalin, F., and Abrun, H.D., Anal. Chem., 1995, vol. 67, p. 3936.

    Article  CAS  Google Scholar 

  58. Harrison, J.A. and Khan, Z.A., J. Electroanal. Chem., 1970, vol. 28, p. 131.

    Article  CAS  Google Scholar 

  59. Galus, Z., Fundamentals of Electrochemical Analysis, New York: Ellis Horwood, 1976, p. 313.

    Google Scholar 

  60. Hallaj, R., Salimi, A., Akhtaric, K., Soltanian, S., and Mamkhezri, H., Sens. Actuat. B, 2009, vol. 135, p. 632.

    Article  CAS  Google Scholar 

  61. Salimi, A. and Pourbeyram, S., Talanta, 2003, vol. 60, p. 205.

    Article  CAS  Google Scholar 

  62. Amini, M.K., Khorasani, J.H., Khaloo, S.S., and Tangestaninejad, S., Anal. Biochem., 2003, vol. 320, p. 32.

    Article  CAS  Google Scholar 

  63. Moreira, A.B., Damos, F.S., Tanaka, A.A., and Kubota, L.T., Pharmaceut, J., Biomed. Anal., 2006, vol. 42, p. 184.

    Article  Google Scholar 

  64. Spataru, N., Sarada, B.V., Popa, E., Tryk, D.A., and Fujishima, A., Anal. Chem., 2001, vol. 73, p. 514.

    Article  CAS  Google Scholar 

  65. Ensafi, A.A. and Behyan, S., Sens. Actuat. B, 2007, vol. 122, p. 282.

    Article  CAS  Google Scholar 

  66. Chen, L. and Ho, K., Sens. Actuat. B, 2008, vol. 130, p. 418.

    Article  CAS  Google Scholar 

  67. Hassan, S.S.M., El-Baz, A.F., and Abd-Rabboh, H.S.M., Anal. Chim. Acta, 2007, vol. 602, p. 108.

    Article  CAS  Google Scholar 

  68. Salimi, A., Hallaj, R., and Amini, M.K., Anal. Chim. Acta, 2005, vol. 534, p. 335.

    Article  CAS  Google Scholar 

  69. Teixeira, M.F.S., Dockal, E.R., and Cavalheiro, E.T.G., Sens. Actuat. B, 2005, vol. 106, p. 619.

    Article  CAS  Google Scholar 

  70. Su, W.Y. and Cheng, S.H., Electrochem. Commun., 2008, vol. 10, p. 899.

    Article  CAS  Google Scholar 

  71. Inoue, T. and Kirchhoff, J.R., Anal. Chem., 2000, vol. 72, p. 5755.

    Article  CAS  Google Scholar 

  72. Filanovsky, B., Anal. Chim. Acta, 1999, vol. 394, p. 91.

    Article  CAS  Google Scholar 

  73. Salimi, A. and Hallaj, R., Talanta, 2005, vol. 66, p. 967.

    Article  CAS  Google Scholar 

  74. Razmi, H., Agazadeh, M., and Habibi, B., J. Electroanal. Chem., 2003, vol. 547, p. 25.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran

    Azadeh Azadbakht & Amir Reza Abbasi

Authors
  1. Azadeh Azadbakht
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Amir Reza Abbasi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Azadeh Azadbakht.

Additional information

Published in Rusian in Elektrokhimiya, 2013, Vol. 49, No. 12, pp. 1256–1269.

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Azadbakht, A., Abbasi, A.R. Fabrication of highly sensitive cysteine electrochemical sensor based on nanostructured compound and carbon nanotube modified electrode. Russ J Electrochem 49, 1127–1138 (2013). https://doi.org/10.1134/S1023193513120021

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193513120021

Keywords

Search

Navigation