Abstract
Proton conductivity of special class of aromatic sulfonic acids is described, in particular, calixarene sulfonic acids that consist of flat anionic layers interlinked by labile two-dimensional hydrogen-bond network. High proton conductivity of their hydrates was observed earlier. The dependence of their transport characteristics (the proton conductivity, the activation energy of conductivity) was shown to have threshold character. The studied systems’ behavior is described on basis of percolation model that assumes changing of the proton transport mechanism at low water content in the structure.
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Vilciauskas, L., Tuckerman, M.E., Bester, G., Paddison, S.J., and Kreuer, K.D., Nature Chem., 2012, vol. 4, p. 461.
Aliev, Z.G., Atovmyan, L.O., Baranova, T.A., and Ukshe, A.E., Russ. J. Struct. Chem., 1995, vol. 36, p. 866.
Pisareva, A.V., Pisarev, R.V., Karelin, A.I., Shmygleva, L.V., Antipin, I.S., Konovalov, A.I., Solov’eva, S.E., Dobrovol’skiy, Yu.A., and Aldoshin, S.M., Izv. Akad. Nauk, Ser. Khim., 2012, p. 1877.
Atwood, J.L., Clark, D.L., Juneja, R.K., Orr, G.W., Robinson, K.D., and Vincent, R.L., J. Am. Chem. Soc., 1992, vol. 114, p. 7558.
Shmygleva, L.B., Pisareva, A.V., Pisarev, R.V., Ukshe, A.E., and Dobrovolsky, Yu.A., Russ. J. Electrochem., 2013, vol. 49, no. 8.
Paddison, S.J., Annu. Rev. Mater. Reactions, 2003, vol. 33, p. 289.
Ukshe, A.E., Pisareva, A.V., Pisarev, R.V., and Dobrovolsky, Yu.A., Int. Baltic Sea Region conference “Functional materials and nanotechnologies”, 2011.
Snarskii, A.A., Bezsudnov, I.V., and Sevryukov, V.A., Protsessy perenosa v makroskopicheski neuporyadochennykh sredakh: Ot teorii srednego polya do perkolyatsii (Transport Processes in Macroscopic Disordered Media: From the Mean-field Theory to percolation), Moscow: LKI, 2007.
Shklovskii, B.I. and Efros, A.L., Elektronnye svoistva sil’no legirovannykh poluprovodnikov (Electronic Properties of Heavily Doped Semiconductors), Moscow: Nauka, 1979.
Snarskii, A.A., Slipchenko, K.V., and Satanin, A.M., Techn. Phys., 2000, vol. 45, p. 194.
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Original Russian Text © A.E. Ukshe, L.V. Shmygleva, A.V. Pisareva, N.G. Bukun, Yu.A. Dobrovol’skii, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 8, pp. 899–904.
After the paper delivered at the XI Meeting “Fundamental Problems of Solid State Ionics” (Chernogolovka, 2012).
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Ukshe, A.E., Shmygleva, L.V., Pisareva, A.V. et al. Percolation model of conductivity of calix[n]arene-p-sulfonic acids. Russ J Electrochem 49, 807–812 (2013). https://doi.org/10.1134/S1023193513080193
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DOI: https://doi.org/10.1134/S1023193513080193