Abstract
The dependence of proton conductivity of 2-sulfobenzoic acid trihydrate on the environmental humidity and temperature is studied. It is shown that trihydrate remains solid when exposed to atmosphere with humidity of up to 65 rel. %. The comparison of 2-sulfobenzoic acid trihydrate with bezoic acid shows that the absence of sulfo group in the benzene ring sharply lowers down the hydrophilic properties of the compound and, correspondingly, its hydration and conductivity.
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Original Russian Text © A.V. Pisareva, R.V. Pisarev, A.I. Karelin, Yu.A. Dobrovol’skii, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 8, pp. 885–892.
This publication was prepared on the basis of a report delivered at the XI Meeting “Fundamental Problems of Solid State Ionics”, Chernogolovka, 2012.
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Pisareva, A.V., Pisarev, R.V., Karelin, A.I. et al. Proton conductivity of benzoic and 2-sulfobenzoic acids. Russ J Electrochem 49, 794–800 (2013). https://doi.org/10.1134/S102319351308017X
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DOI: https://doi.org/10.1134/S102319351308017X