Skip to main content
SpringerLink
Log in

Synthesis, structure, and impedance spectra of iron-containing bismuth titanates

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Iron-containing bismuth titanates with a cubic pyrochlore Bi1.6Fe x Ti2O7 − δ structure were synthesized by the ceramic method. The region in which iron-containing pyrochlores are formed was determined. The pycnometric specific gravity of the samples was measured. Based on XRD and pycnometric specific gravity data, it was concluded that iron atoms lie in the bismuth sublattice. The electric properties of the materials were studied by high-temperature impedance spectroscopy. A strong effect of polarization on the impedance spectra was found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lau, G.C., Muegge, B.D., McQueen, T.M., Duncan, E.L., and Cava, R.J., J. Solid State Chem., 2006, vol. 179, p. 3126.

    Article  CAS  Google Scholar 

  2. Abrantes, J.C.C., Levchenko, A.V., Shlyakhtina, A.V., Shcherbakova, L.G., Horovistiz, A.L., Fragg, D.P., and Frade, J.R., Solid State Ionics, 2006, vol. 177, p. 1785.

    Article  CAS  Google Scholar 

  3. Shlyakhtina, A.V., Abrantes, J.C.C., Larina, L.L., and Shcherbakova, L.G., Solid State Ionics, 2005, vol. 176, p. 1653.

    Article  CAS  Google Scholar 

  4. Filoti, G., Rosenberg, M., Kuncser, V., Seling, B., Fries, T., Spies, A., and Kemmler-Sack, S., J. Alloys Compd., 1998, vol. 268, p. 16.

    Article  CAS  Google Scholar 

  5. Vanderah, T.A., Lufaso, M.W., Adler, A.U., Levin, I., Nino, J.C., Provenzano, V., and Schenck, P.K., J. Solid State Chem., 2006, vol. 179, p. 3467.

    Article  CAS  Google Scholar 

  6. Lufaso, M.W., Vanderah, T.A., Pazos, I.M., Levin, I., Roth, R.S., Nino, J.C., Provenzano, V., and Schenck, P.K., J. Solid State Chem., 2006, vol. 179, p. 3900.

    Article  CAS  Google Scholar 

  7. Withers, R.L., Welberry, T.R., Larsson, A.K., Liu, Y., Noren, L., Rundlof, H., and Brink, F.J., J. Solid State Chem., 2004, vol. 177, p. 231.

    Article  CAS  Google Scholar 

  8. Nguyen, H.B., Norén, L., Liua, Y., Withersa, R.L., Weib, X., and Elcombec, M.M., J. Solid State Chem., 2007, vol. 180, p. 2558.

    Article  CAS  Google Scholar 

  9. Piir, I.V., Sekushin, N.A., Grass, V.E., Ryabkov, Y.I., Chezhina, N.V., Nekipelov, S.V., Sivkov, V.N., and Vyalikh, D.V., Solid State Ionics, 2012, vol. 225, p. 446.

    Article  Google Scholar 

  10. Hector, A.L. and Wiggin, S.B., J. Solid State Chem., 2004, vol. 177, p. 139.

    Article  CAS  Google Scholar 

  11. Esquivel-Elizondo, J.R., Hinojosa, B.B., and Nino, J.C., Chem. Mater., 2011, vol. 23, p. 4965.

    Article  CAS  Google Scholar 

  12. Sekushin, N.A., Russ. J. Electrochem., 2009, vol. 45, p. 1300.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, Syktyvkar, Russia

    I. V. Piir, M. S. Koroleva, N. A. Sekushin, V. E. Grass & Yu. I. Ryabkov

Authors
  1. I. V. Piir
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. S. Koroleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Sekushin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. E. Grass
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. I. Ryabkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. V. Piir.

Additional information

Original Russian Text © I.V. Piir, M.S. Koroleva, N.A. Sekushin, V.E. Grass, Yu.I. Ryabkov, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 8, pp. 909–914.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Piir, I.V., Koroleva, M.S., Sekushin, N.A. et al. Synthesis, structure, and impedance spectra of iron-containing bismuth titanates. Russ J Electrochem 49, 817–821 (2013). https://doi.org/10.1134/S1023193513080168

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193513080168

Keywords

Search

Navigation