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Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm2S4

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Abstract

Solid solutions of Sm2S3 and Tm2S3 based on BaSm2S4 (the structural type of CaFe2O4) are obtained. The samples are studied using microprobe analysis and the XRD technique. The length of the solid solution region is determined. The type of ion conductivity and thermodynamics of dissolution of the binary sulfides of Sm2S3 and Tm2S3 in BaSm2S4 are studied. Partial molar enthalpies of dissolution of binary sulfides in basic thiosamarate are determined. A possible mechanism of defect formation is suggested.

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Authors and Affiliations

  1. Vyatka State University, ul. Moskovskaya 36, Kirov, 610000, Russia

    T. V. Mikhailichenko, L. A. Kalinina & Yu. N. Ushakova

  2. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    I. V. Murin

Authors
  1. T. V. Mikhailichenko
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  2. L. A. Kalinina
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  3. Yu. N. Ushakova
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  4. I. V. Murin
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Correspondence to T. V. Mikhailichenko.

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Original Russian Text © T.V. Mikhailichenko, L.A. Kalinina, Yu.N. Ushakova, I.V. Murin, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 8, pp. 865–871.

Published on the basis of the lecture in XI Meeting “Fundamental Problems of Solid State Ionics”, Chernogolovka, 2012.

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Mikhailichenko, T.V., Kalinina, L.A., Ushakova, Y.N. et al. Ion conductivity type and thermodynamics of dissolution of binary sulfides Sm2S3 and Tm2S3 in BaSm2S4 . Russ J Electrochem 49, 776–782 (2013). https://doi.org/10.1134/S1023193513080132

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  • DOI: https://doi.org/10.1134/S1023193513080132

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