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Electrochemical characteristics of propylene carbonate solutions of tetraethylammonium tetrafluoroborate

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Abstract

The specific and molar electric conductivities of propylene carbonate solutions of Et4NBF4 with concentrations of 0.15–1.4 m were determined at 283.15, 298.15, and 313.15 K. The temperature dependence of the electric conductivity of the system was analyzed. The concentration dependence of electric conductivity was described in terms of the Castell-Amis equation. A comparative analysis of the charge transfer in Et4NBF4 and LiAsF6 systems in propylene carbonate was performed using the concept of quasicrystallinity of concentrated electrolyte solutions. The range of potentials in which the electrolyte solutions are stable on a platinum electrode was determined.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    E. Yu. Tyunina & V. N. Afanasiev

  2. Ivanovo State University of Architecture and Construction, Ivanovo, Russia

    M. D. Chekunova

Authors
  1. E. Yu. Tyunina
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  2. M. D. Chekunova
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  3. V. N. Afanasiev
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Correspondence to E. Yu. Tyunina.

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Original Russian Text © E.Yu. Tyunina, M.D. Chekunova, V.N. Afanasiev, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 5, pp. 509–514.

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Tyunina, E.Y., Chekunova, M.D. & Afanasiev, V.N. Electrochemical characteristics of propylene carbonate solutions of tetraethylammonium tetrafluoroborate. Russ J Electrochem 49, 453–457 (2013). https://doi.org/10.1134/S1023193513050157

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  • DOI: https://doi.org/10.1134/S1023193513050157

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