Skip to main content
SpringerLink
Log in

Zero charge potentials of platinum metals and electron work functions (Review)

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The methods of determining the potentials of zero total charge (ZTCP) and zero free charge (ZFCP) of platinum metals are considered. Special attention is paid to the CO displacement technique developed in the recent 15 years. This method allows directly determining the so called zero displaced charge potentials (ZDCP) that for many systems are close to ZTCP. The published experimental data are tabulated by values of ZTCP/ZDCP for electrodes of smooth polycrystalline and dispersed (electrolytic deposits) metals; single crystal faces; stepped surfaces with different step density; adatom layers of platinum metals on well characterized ordered supports; single crystal faces decorated by foreign adatoms; nanoparticles with the given surface structure, controlled shape, or given size. The concepts of global and local zero charge potential values (ZCP) are analyzed. The effect of the composition and surface structure, solution composition and pH, electrode pretreatment conditions on the ZCP values is discussed. Special attention is paid to the results of determination of ZTCP and ZFCP of the most intriguing interface: Pt(111)/solution of electrolyte. The necessity is emphasized of detailed studies of the size dependence of ZCP as an important aspect of nanoelectrochemistry. In the cases when the corresponding data are accessible, the values of ZCP and electron work function are compared. It is assumed that such comparison in the case of platinum metals can refer both to ZTCP/ZDCP and ZFCP. The results of comparison are discussed with account for the contributions of solution ions, hydrogen atoms, and water molecules to potential drops at interfaces.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Frumkin, A. and Gorodetzkaja, A., Z. Phys. Chem., 1928, vol. 136, p. 451.

    CAS  Google Scholar 

  2. Frumkin, A.N., Potentsialy nulevogo zaryada (Zero Charge Potentials), Moscow: Nauka, 1979.

    Google Scholar 

  3. Trasatti, S., Electrochim. Acta, 1987, vol. 32, p. 843.

    Article  CAS  Google Scholar 

  4. Trasatti, S., Electrochim. Acta, 1990, vol. 35, p. 269.

    Article  CAS  Google Scholar 

  5. Trasatti, S., Electrochim. Acta, 1991, vol. 36, p. 1659.

    Article  CAS  Google Scholar 

  6. Trasatti, S. and Dubova, L.M., J. Chem. Soc., Faraday Trans., 1995, vol. 91, p. 3311.

    Article  CAS  Google Scholar 

  7. Trasatti, S., Surf. Sci., 1995, vol. 335, p. 1.

    Article  CAS  Google Scholar 

  8. Emets, V.V. and Damaskin, B.B., Russ. J. Electrochem., 2009, vol. 45, p. 45.

    Article  CAS  Google Scholar 

  9. Damaskin, B.B. and Petrii, O.A., J. Solid State Electrochem., 2011, vol. 15, p. P. 1317.

    Article  CAS  Google Scholar 

  10. Ramirez, P., Andreu, R., Calzado, C.J., and Calvente, J.J., Anal. Chem., 2007, vol. 79, p. 6473.

    Article  CAS  Google Scholar 

  11. Clavilier, J., J. Electroanal. Chem, 1980, vol. 107, p. 211.

    Article  CAS  Google Scholar 

  12. Clavilier, J., Faure, R., Guinet, G., and Durand, R., J. Electroanal. Chem., 1980, vol. 107, p. 205.

    Article  CAS  Google Scholar 

  13. Climent, V., Garcia-Araez, N., Herrero, E., and Feliu, J., Russ. J. Electrochem., 2006, vol. 42, p. 1145.

    Article  CAS  Google Scholar 

  14. Climent, V. and Feliu, J., J. Solid State Electrochem., 2011, vol. 15, p. P. 1297.

    Article  CAS  Google Scholar 

  15. Wandelt, K., Appl. Surf. Sci., 1997, vol. 111, p. 1.

    Article  CAS  Google Scholar 

  16. Jia, J.F., Inoue, K., Hasegawa, Y., Yang, W.S., and Sakurai, T., J. Vac. Sci. Technol., 1997, vol. 15, p. 186.

    Article  Google Scholar 

  17. Jia, J.F., Inoue, K., Hasegawa, Y., Yang, W.S., and Sakurai, T., Phys.Rev. B: Condens. Mater., 1998, vol. 58, p. 1193.

    Article  CAS  Google Scholar 

  18. Trasatti, S. and Lust, E., in Modern Aspects of Electrochemistry, White, R.E and et al., Eds., New York: Kluwer Academic/Plenum Publ, 1999, vol. 33, p. 1.

  19. Frumkin, A.N. and Petrii, O.A., Electrochim. Acta, 1970, vol. 15, p. 391.

    Article  CAS  Google Scholar 

  20. Frumkin, A.N., Petrii, O.A., and Damaskin, B.B., J. Electroanal. Chem., 1970, vol. 27, p. 81.

    Article  CAS  Google Scholar 

  21. Frumkin, A.N., Petrii, O.A., and Damaskin, B.B., Elektrokhimiya, 1970, vol. 6, p. 614.

    CAS  Google Scholar 

  22. Frumkin, A.N. and Petrii, O.A., Electrochim. Acta, 1975, vol. 20, p. 347.

    Article  CAS  Google Scholar 

  23. Petrii, O.A., Usp. Khim., 1975, vol. 4, p. 2048.

    Google Scholar 

  24. Petrii, O.A., Itogi Nauki Tekhn., Ser.: Elektrokhim., 1977, vol. 12, p. 56.

    CAS  Google Scholar 

  25. Petrii, O.A., The Modern Theory of Electrocapillarity, Rusanov, A.I. and Gudrich, F.Ch., Eds., Berlin: Akad. Verlag, 1981, p. 141.

  26. Frumkin, A.N. and Shlygin, A.I., Izv. AN SSSR. Otd. Fiz.-Mat. Estestv. Nauk, 1936, p. 773.

    Google Scholar 

  27. Frumkin, A. and Slygin, A., Acta Physicochim. URSS, 1936, vol. 5, p. 819.

    CAS  Google Scholar 

  28. Petrii, O.A., Marvet, R.V., and Frumkin, A.N., Elektrokhimiya, 1967, vol. 3, p. 116.

    CAS  Google Scholar 

  29. Frumkin, A.N. and Petrii, O.A., Kolotyrkina (Safonova) T.Ya, Elektrokhimiya, 1974, vol. 10, p. 1741.

    CAS  Google Scholar 

  30. Petrii, O.A., Nguen Van Tue, and Kotlov, Yu.G., Elektrokhimiya, 1969, vol. 5, p. 1108.

    CAS  Google Scholar 

  31. Frumkin, A.N., Petrii, O.A., and Kotlov, Yu.G., Elektrokhimiya, 1969, vol. 5, p. 1214.

    CAS  Google Scholar 

  32. Slygin, A., Frumkin, A., and Medwedowsky, V., Acta Physicochim. URSS, 1936, vol. 4, p. 911.

    Google Scholar 

  33. Balashova, N.A., Dokl. Akad. Nauk SSSR, 1955, vol. 103, p. 639.

    CAS  Google Scholar 

  34. Balashova, N.A. and Kazarinov, V.E., in Electroanal. Chem., Bard, A.J., Ed., New York: Marcel Dekker, 1969, vol. 3, p. 135.

  35. Albalat, R., Gomez, R., Orts, J.M., Feliu, J.M., and Aldaz, A., J. Electroanal. Chem., 1992, vol. 330, p. 489.

    Article  Google Scholar 

  36. Clavilier, J., Albalat, R., Gomez, R., Orts, J.M., and Feliu, J.M., J. Electroanal. Chem., 1993, vol. 360, p. 325.

    Article  CAS  Google Scholar 

  37. Feliu, J.M., Orts, J.M., Gomez, R., Aldaz, A., and Clavilier, J., J. Electroanal. Chem., 1994, vol. 372, p. 265.

    Article  CAS  Google Scholar 

  38. Herrero, E., Feliu, J.M., Wieckowski, A., and Clavilier, J., Surf. Sci., 1995, vol. 325, p. 131.

    Article  CAS  Google Scholar 

  39. Climent, V., Gomez, R., Orts, J.M., Aldaz, A., and Feliu, J.M., Electrochem. Soc. Proc., Korzeniewski, C. and Conway, B.E., Eds., Pennington, New Jersey: The Electrochem. Soc. (publ.), Pennington, 1997, vol. 97–17, p. 222.

    Google Scholar 

  40. Gomez, R., Feliu, J.M., Aldaz, A., and Weaver, M.J., Surf. Sci., 1998, vol. 410, p. 48.

    Article  CAS  Google Scholar 

  41. Climent, V., Gomez, R., Orts, J.M., Aldaz, A., and Feliu, J.M., in Interfacial Electrochemistry, Wieckowski, A., Ed., New York: M. Dekker, 1999, p. 463.

  42. Weaver, M.J., Langmuir, 1998, vol. 14, p. 3932.

    Article  CAS  Google Scholar 

  43. Climent, V., Gomez, R., and Feliu, J.M., Electrochim. Acta, 1999, vol. 45, p. 629.

    Article  CAS  Google Scholar 

  44. Gomez, R., Climent, V., Feliu, J.M., and Weaver, M.J., J. Phys. Chem. B, 2000, vol. 104, p. 597.

    Article  CAS  Google Scholar 

  45. Alvarez, B., Climent, V., Feliu, J.M., and Aldaz, A., Electrochem. Commun., 2000, vol. 2, p. 427.

    Article  CAS  Google Scholar 

  46. Alvarez, B., Climent, V., Rodes, A., and Feliu, J.M., J. Electroanal. Chem., 2001, vol. 497, p. 125.

    Article  CAS  Google Scholar 

  47. Alvarez, B., Climent, V., Rodes, A., and Feliu, J.M., Phys. Chem. Chem. Phys., 2001, vol. 3, p. 3269.

    Article  CAS  Google Scholar 

  48. Attard, G.A. and Feliu, J.M., J. Electroanal. Chem., 2002, vol. 532, p. 67.

    Article  Google Scholar 

  49. Herrero, E., Mostany, J., Feliu, J.M., and Lipkowski, J., J. Electroanal. Chem., 2002, vol. 534, p. 79.

    Article  CAS  Google Scholar 

  50. Domke, K., Herrero, E., Rodes, A., and Feliu, J.M., J. Electroanal. Chem., 2003, vol. 552, p. 115.

    Article  CAS  Google Scholar 

  51. Mostany, J., Herrero, E., Feliu, J.M., and Lipkowski, J., J. Electroanal. Chem., 2003, vol. 558, p. 19.

    Article  CAS  Google Scholar 

  52. Garcia-Araez, N., Climent, V., Herrero, E., and Feliu, J.M., Surf. Sci., 2004, vol. 560, p. 269.

    Article  CAS  Google Scholar 

  53. Attard, G.A., Hazzazi, O., Wells, P.B., Climent, V., Herrero, E., and Feliu, J.M., J. Electroanal. Chem., 2004, vol. 568, p. 329.

    Article  CAS  Google Scholar 

  54. Garcia-Araez, N., Climent, V., Herrero, E., Feliu, J.M., and Lipkowski, J., J. Electroanal. Chem., 2005, vol. 576, p. 33.

    Article  CAS  Google Scholar 

  55. Garcia-Araez, N., Climent, V., Herrero, E., Feliu, J.M., and Lipkowski, J., J. Electroanal. Chem., 2005, vol. 582, p. 76.

    Article  CAS  Google Scholar 

  56. Garcia-Araez, N., Climent, V., Herrero, E., Feliu, J.M., and Lipkowski, J., J. Electroanal. Chem., 2006, vol. 591, p. 149.

    Article  CAS  Google Scholar 

  57. Garcia-Araez, N., Climent, V., Herrero, E., Feliu, J.M., and Lipkowski, J., Electrochim. Acta, 2006, vol. 51, p. 3787.

    Article  CAS  Google Scholar 

  58. Mostany, J., Herrero, E., Feliu, J.M., and Lipkowski, J., J. Phys. Chem. B, 2002, vol. 106, p. 12787.

    Article  CAS  Google Scholar 

  59. Garcia-Araez, N., Climent, V., Rodriguez, P., and Feliu, J.M., Electrochim. Acta, 2008, vol. 53, p. 6793.

    Article  CAS  Google Scholar 

  60. Berna, A., Feliu, J.M., Gancs, L., and Mukerjee, S., Electrochem. Commun., 2008, vol. 10, p. 1695.

    Article  CAS  Google Scholar 

  61. Garcia-Araez, N., Climent, V., and Feliu, J.M., J. Solid State Electrochem., 2008, vol. 12, p. 387.

    Article  CAS  Google Scholar 

  62. Souza-Garcia, J., Climent, V., and Feliu, J.M., Electrochem. Commun., 2009, vol. 11, p. 1515.

    Article  CAS  Google Scholar 

  63. Garcia-Araez, N., Climent, V., and Feliu, J.M., J. Phys. Chem. C, 2009, vol. 113, p. 9290.

    Article  CAS  Google Scholar 

  64. Mostany, J., Martinez, P., Climent, V., Herrero, E., and Feliu, J.M., Electrochim. Acta, 2009, vol. 54, p. 5836.

    Article  CAS  Google Scholar 

  65. Souza-Garcia, J., Berna, A., Ticianelli, E.A., Climent, V., and Feliu, J.M., J. Electroanal.Chem., 2011, vol. 660, p. 276.

    Article  CAS  Google Scholar 

  66. Mayrhofer, K.J.J., Blizanac, B.B., Arenz, M., Stamenkovic, V.R., Ross, P.N., and Markovic, N.M., J. Phys. Chem. B, 2005, vol. 109, p. 14433.

    Article  CAS  Google Scholar 

  67. Cuesta, A., Surf. Sci., 2004, vol. 572, p. 11.

    Article  CAS  Google Scholar 

  68. Hara, M., Linke, U., and Wandlowski, Th., Electrochim. Acta, 2007, vol. 52, p. 5733.

    Article  CAS  Google Scholar 

  69. Xu, Q., Linke, U., Bujak, R., and Wandlowski, Th., Electrochim. Acta, 2009, vol. 54, p. 5509.

    Article  CAS  Google Scholar 

  70. Rudnev, A.V. and Wandlowski, T., Russ. J. Electrochem., 2012, vol. 48, p. 259.

    Article  CAS  Google Scholar 

  71. Chen, Q.-S., Solla-Gullon, J., Sun, Sh.-G., and Feliu, J.M., Electrochim. Acta, 2010, vol. 55, p. 7982.

    Article  CAS  Google Scholar 

  72. Markovic, N.M., Lucas, C.A., Rodes, A., Stamenkovic, V., and Ross, P.N., Surf. Sci., 2002, vol. 499, p. L149.

    Article  CAS  Google Scholar 

  73. Willsau, J. and Heitbaum, J., Electrochim. Acta, 1986, vol. 31, p. 943.

    Article  CAS  Google Scholar 

  74. Podlovchenko, B.I. and Kolyadko, E.A., J. Electroanal. Chem., 2003, vol. 506, p. 1121.

    Google Scholar 

  75. Podlovchenko, B.I., Russ. J. Electrochem., 2004, vol. 40, p. 1132.

    Article  CAS  Google Scholar 

  76. Markovich, N.M., Grgur, B.N., Lucas, C.A., and Ross, P.N., J. Phys. Chem. B, 1999, vol. 103, p. 487.

    Article  Google Scholar 

  77. Markovich, N.M. and Ross, P.N., Surf. Sci. Rep., 2005, vol. 45, p. 117.

    Article  Google Scholar 

  78. Lopez-Cudero, A., Cuesta, A., and Gutierrez, C., J. Electroanal. Chem., 2003, vol. 548, p. 109.

    Article  CAS  Google Scholar 

  79. Lopez-Cudero, A., Cuesta, A., and Gutierrez, C., J. Electroanal. Chem., 2006, vol. 586, p. 204.

    Article  CAS  Google Scholar 

  80. Cuesta, A., Couto, A., Rincon, A., Perez, M.C., Lopez-Cudero, A., and Gutierrez, C., J. Electroanal. Chem., 2006, vol. 586, p. 184.

    Article  CAS  Google Scholar 

  81. Jakuszewski, B. and Kozlowski, Z., Roszn. Chem., 1964, vol. 38, p. 93.

    CAS  Google Scholar 

  82. Stern, D.A., Baltruschat, H., Martinez, M., Stickney, J.L., Frank, A.T., and Hubbard, A.T., J. Electroanal. Chem., 1987, vol. 217, p. 101.

    Article  CAS  Google Scholar 

  83. Baltruschat, H., Martinez, M., Lewis, S.K., Lu, F., Song, D., Stern, D.A., Datta, A., and Hubbard, A.T., J. Electroanal. Chem., 1987, vol. 217, p. 111.

    Article  CAS  Google Scholar 

  84. Salaita, G.N., Stern, D.A., Lu, F., Baltruschat, H., Schardt, B.C., Stickney, J.L., Soriaga, M.P., Frank, D.G., and Hubbard, A.T., Langmuir, 1996, vol. 2, p. 828.

    Article  Google Scholar 

  85. Hamm, U.W., Kramer, D., Zhai, R.S., and Kolb, D., J. Electroanal. Chem., 1996, vol. 414, p. 85.

    Article  Google Scholar 

  86. Attard, G.A. and Ahmadi, A., J. Electroanal. Chem., 1995, vol. 389, p. 175.

    Article  Google Scholar 

  87. Frumkin, A.N., Nikolaeva, N.V., and Shapiro, N.S., Dokl. Akad. Nauk SSSR, 1952, vol. 86, p. 581.

    Google Scholar 

  88. Frumkin, A., Sven. Kem. Tidskr, 1965, vol. 77, p. 300.

    CAS  Google Scholar 

  89. Climent, V., Marcia, M.D., Herrero, E., Feliu, J.M., and Petrii, O.A., J. Electroanal. Chem., 2008, vol. 612, p. 269.

    Article  CAS  Google Scholar 

  90. Botukhova, G.N. and Petrii, O.A., Russ. J. Electrochem., 2013, vol. 49 (in press).

  91. Frumkin, A.N., Dokl. Akad. Nauk SSSR, 1964, vol. 154, p. 1432.

    CAS  Google Scholar 

  92. Seo, M. and Serizawa, Y., J. Electrochem. Soc., 2003, vol. 150, p. E472.

    Article  CAS  Google Scholar 

  93. Tsirlina, G.A., in Modern Aspects of Electrochemistry, Vayenas, C., et al., Eds., New York: Springer, 2010, vol. 49, p. 107.

  94. Iwasita, T. and Xia, X., J. Electroanal. Chem., 1996, vol. 411, p. 95.

    Article  Google Scholar 

  95. Wagner, F.T. and Moylan, T.E., Surf. Sci, 1988, vol. 206, p. 187.

    Article  CAS  Google Scholar 

  96. Benderskii, V.A. and Velicko, G.I., J. Electroanal. Chem., 1982, vol. 140, p. 1.

    Article  CAS  Google Scholar 

  97. Climent, V., Coles, B.A., and Compton, R.G., J. Phys. Chem. B, 2002, vol. 106, pp. 5258, 5988.

    Article  CAS  Google Scholar 

  98. Coles, B.A., Compton, R.G., and Feliu, J.M., J. Electroanal. Chem., 2004, vol. 561, p. 157.

    Article  CAS  Google Scholar 

  99. Climent, V., Garcia-Araez, N., Compton, R.G., and Feliu, J.M., J. Phys. Chem. B, 2006, vol. 110, p. 21092.

    Article  CAS  Google Scholar 

  100. Garcia-Araez, N., Climent, V., and Feliu, J.M., J. Am. Chem. Soc., 2008, vol. 130, p. 3824.

    Article  CAS  Google Scholar 

  101. Garcia-Araez, N., Climent, V., and Feliu, J.M., Electrochim. Acta, 2009, vol. 54, p. 966.

    Article  CAS  Google Scholar 

  102. Garcia-Araez, N., Climent, V., and Feliu, J.M., J. Electroanal. Chem., 2010, vol. 649, p. 69.

    Article  CAS  Google Scholar 

  103. Garcia-Araez, N., Climent, V., and Feliu, J.M., Russ. J. Electrochem, 2012, vol. 48, p. 271.

    Article  CAS  Google Scholar 

  104. Frumkin, A.N., J. Res. Inst. Catal. Hokkaido Univ, 1967, vol. 15, p. 61.

    CAS  Google Scholar 

  105. Valette, G. and Hamelin, A., J. Electroanal. Chem., 1973, vol. 45, p. 301.

    Article  CAS  Google Scholar 

  106. Besocke, K., Krahl-Urban, B., and Wagner, H., Surf. Sci., 1977, vol. 68, p. 3.

    Article  Google Scholar 

  107. Smoluchowski, R., Phys. Rev., 1941, vol. 60, p. 661.

    Article  CAS  Google Scholar 

  108. Merrick, I., Inglesfield, J.E., and Attard, G.A., Phys. Rev., vol. 71, p. 085407.

  109. Lecouer, J., Andro, J., and Parsons, R., Surf. Sci., 1982, vol. 114, p. 320.

    Article  Google Scholar 

  110. Ross, Jr.P.N., J. Chim. Phys. Phys.-Chim. Biol., 1991, vol. 68, p. 1353.

    Google Scholar 

  111. Parsons, R. and Ritzoulis, G., J. Electroanal. Chem., 1991, vol. 318, p. 1.

    Article  CAS  Google Scholar 

  112. Lang, B., Joyner, R.W., and Somorjai, G.A., Surf. Sci., 1972, vol. 30, p. 440.

    Article  CAS  Google Scholar 

  113. Motoo, S. and Furuya, N., Ber. Bunsen-Ges. Phys. Chem., 1987, vol. 91, p. 457.

    CAS  Google Scholar 

  114. Markovic, N.M., Marinkovic, N.S., and Adzic, R.R., J. Electroanal. Chem., 1988, vol. 241, p. 399.

    Google Scholar 

  115. Attard, G.A. and Bannister, A., J. Electroanal. Chem., 1991, vol. 300, p. 467.

    Article  CAS  Google Scholar 

  116. Clavilier, J., Llorca, M.J., Feliu, J.M., and Aldaz, A., J. Electroanal. Chem., 1991, vol. 310, p. 429.

    Article  CAS  Google Scholar 

  117. Llorca, M.J., Feliu, M.J., Aldaz, A., and Clavilier, J., J. Electroanal. Chem., 1994, vol. 376, p. 151.

    Article  CAS  Google Scholar 

  118. AlAkl, A. and Attard, G.A., J. Phys. Chem. B, 1997, vol. 101, p. 4597.

    Article  CAS  Google Scholar 

  119. Gomez, R., Rodes, A., Perez, J.M., Feliu, J.M., and Aldaz, A., Surf. Sci., 1995, vol. 344, p. 85.

    Article  CAS  Google Scholar 

  120. Climent, V., Markovic, N.M., and Ross, P.N., J. Phys. Chem. B, 2000, vol. 104, p. 3116.

    Article  CAS  Google Scholar 

  121. Markovic, N.M., Lucas, C.A., Climent, V., Stamenkovic, V., and Ross, P.N., Surf. Sci., 2000, vol. 465, p. 103.

    Article  CAS  Google Scholar 

  122. Baldauf, M. and Kolb, D.M., J. Phys. Chem, 1996, vol. 100, p. 11375.

    Article  CAS  Google Scholar 

  123. Kibler, L.A., Kleinert, M., Raqndler, R., and Kolb, D.N., Surf. Sci., 1999, vol. 443, p. 19.

    Article  CAS  Google Scholar 

  124. Kibler, L.A., El-Aziz, A.M., and Kolb, D.M., J. Molec. Catal. A: Chem., 2003, vol. 199, p. 57.

    Article  CAS  Google Scholar 

  125. Herrero, E., Franaszczuk, K., and Wieckowski, A., J. Electroanal. Chem., 1993, vol. 361, p. 269.

    Article  CAS  Google Scholar 

  126. Chrzanowski, W. and Wieckowski, A., Langmuir, 1997, vol. 13, p. 5974.

    Article  CAS  Google Scholar 

  127. Inukai, J. and Ito, M., J. Electroanal. Chem., 1993, vol. 358, p. 307.

    Article  CAS  Google Scholar 

  128. Gomez, R., Rodes, A., Perez, J.M., Feliu, J.M., and Aldaz, A., Surf. Sci., 1995, vol. 327, p. 202.

    Article  CAS  Google Scholar 

  129. Attard, G.A., Price, R., and AlAkl, A., Surf. Sci., 1995, vol. 335, p. 52.

    Article  CAS  Google Scholar 

  130. Gomez, R. and Feliu, J.M., Electrochim.Acta, 1998, vol. 44, p. 1191.

    Article  CAS  Google Scholar 

  131. de Dios, F.J., Gomez, R., and Feliu, J.M., Langmuir, 2005, vol. 21, p. 7439.

    Article  CAS  Google Scholar 

  132. Alvarez, B., Berna, A., Rodes, A., and Feliu, J.M., Surf. Sci., 2004, vol. 573, p. 32.

    Article  CAS  Google Scholar 

  133. Climent, V., Alvarez, B., Feliu, J.M., and Aldaz, A., Electrochem. Commun., 2000, vol. 2, p. 427.

    Article  Google Scholar 

  134. Frumkin, A.N., Malysheva, Zh.N., Petrii, O.A., and Kazarinov, V.E., Elektrokhimiya, 1972, vol. 8, p. 599.

    CAS  Google Scholar 

  135. Herrero, E., Climent, V., and Feliu, J.M., Electrochem. Commun., 2000, vol. 2, p. 636.

    Article  CAS  Google Scholar 

  136. Climent, V., Herrero, E., and Feliu, J.M., Electrochem. Commun., 2001, vol. 3, p. 590.

    Article  CAS  Google Scholar 

  137. Vorsina, M.A. and Frumkin, A.N., Dokl. Akad. Nauk SSSR, 1939, vol. 24, p. 918.

    CAS  Google Scholar 

  138. Kheifets, V.L. and Krasikov, V.S., Dokl. Akad. Nauk SSSR, 1956, vol. 109, p. 586.

    CAS  Google Scholar 

  139. Frumkin, A.N., Balashova, N.A., and Kazarinov, V.E., J. Electrochem. Soc., 1966, vol. 113, p. 1011.

    Article  CAS  Google Scholar 

  140. Petrii, O.A., Safonov, V.A., and Shchigorev, I.G., Elektrokhimiya, 1973, vol. 9, p. 125.

    CAS  Google Scholar 

  141. Henderson, M.A., Surf. Sci. Rep., 2002, vol. 46, p. 5.

    Article  Google Scholar 

  142. Osawa, M., Tsushima, M., Mogami, H., Samjeske, G., and Yamakata, A., J. Phys. Chem., 2008, vol. 112, p. 4248.

    CAS  Google Scholar 

  143. Ito, M., Surf. Sci. Rep., 2008, vol. 63, p. 329.

    Article  CAS  Google Scholar 

  144. Pajkossy, T. and Kolb, D.M., Electrochim. Acta, 2001, vol. 46, p. 3063.

    Article  CAS  Google Scholar 

  145. Kerner, Z., Pajkossy, T., Kibler, L.A., and Kolb, D.M., Electrochem. Commun., 2002, vol. 4, p. 787.

    Article  CAS  Google Scholar 

  146. Pajkossy, T. and Kolb, D.M., Electrochem. Commun., 2003, vol. 5, p. 283.

    Article  CAS  Google Scholar 

  147. Pajkossy, T., Kibler, L.A., and Kolb, D.M., J. Electroanal. Chem., 2005, vol. 582, p. 69.

    Article  CAS  Google Scholar 

  148. Pajkossy, T., Kibler, L.A., and Kolb, D.M., J. Electroanal. Chem., 2007, vol. 600, p. 113.

    Article  CAS  Google Scholar 

  149. Pajkossy, T. and Kolb, D.M., Russ. J. Electrochem., 2009, vol. 45, p. 29.

    Article  CAS  Google Scholar 

  150. Pajkossy, T. and Kolb, D., Electrochim. Acta, 2009, vol. 54, p. 3594.

    Article  CAS  Google Scholar 

  151. Pajkossy, T. and Kolb, D.M., Electrochim. Acta, 2008, vol. 53, p. 7403.

    Article  CAS  Google Scholar 

  152. El-Aziz, A.M., Kibler, L.A., and Kolb, D.M., Electrochem. Commun., 2002, vol. 4, p. 535.

    Article  CAS  Google Scholar 

  153. El-Aziz, A.M., Hoyer, R., Kibler, L.A., and Kolb, D.M., Electrochim. Acta, 2006, vol. 51, p. 2518.

    Article  CAS  Google Scholar 

  154. Vasina, S.Ya. and Petrii, O.A., Elektrokhimiya, 1970, vol. 6, p. 242.

    CAS  Google Scholar 

  155. Lang, G.G., Sas, N.S., Ujvari, M., and Horanyi, G., Electrochim. Acta, 2003, vol. 552, p. 197.

    CAS  Google Scholar 

  156. Gomez, R. and Weaver, M.J., Langmuir, 1998, vol. 14, p. 2525.

    Article  CAS  Google Scholar 

  157. Rhee, K., Wasberg, M., Zelenay, P., and Wieckowski, A., Catal. Lett., 1991, vol. 10, p. 49.

    Article  Google Scholar 

  158. Langkau, T. and Baltruschat, H., Electrochim. Acta, 2002, vol. 47, p. 1595.

    Article  CAS  Google Scholar 

  159. Frumkin, A.N., Petrii, O.A., and Grigor’ev, N.B., in Elektrokhimiya i rasplavy (Electrochemistry and Melts), Moscow: Nauka, 1974, p. 31; Trudy Sverdlovskogo Instituta Khimii (Proceedings of Sverdlovsk Institute of Chemistry), Sverdlovsk, 1975, pp. 65–71.

    Google Scholar 

  160. Frumkin, A.N., Petrii, O.A., Kossaya, A.M., Entina, V.S., and Topolev, V.V., J. Electroanal. Chem., 1968, vol. 16, p. 175.

    Article  CAS  Google Scholar 

  161. Petrii, O.A. and Grafov, B.M., Elektrokhimiya, 1973, vol. 9, p. 852.

    CAS  Google Scholar 

  162. Petrii, O.A., Ushmaev, A.V., and Safonova, T.Ya., Elektrokhimiya, 1977, vol. 13, p. 745.

    CAS  Google Scholar 

  163. Garcia-Araez, N., Climent, V., Rodrigez, P., and Feliu, J.M., Langmuir, 2010, vol. 26, p. 12408.

    Article  CAS  Google Scholar 

  164. Frumkin, A.N., Petrii, O.A., and Kolotyrkina-Safonova, T.Ya., Dokl. Akad. Nauk SSSR, 1975, vol. 222, p. 1159.

    CAS  Google Scholar 

  165. Notoya, R. and Petrii, O.A., Dokl. Akad. Nauk SSSR, 1976, vol. 226, p. 133.

    Google Scholar 

  166. Petrii, O.A. and Safonova, T.Ya., in Dvoinoi sloi i adsorbtsiya na tverdykh elektrodakh. Materialy Vsesoyuznogo simp. (Double Layer and Adsorption on Solid Electrodes. Materials of All-Union Symposium), Tartu: Izd-vo Tart. gos. un-ta, 1975, vol. IV, p. 234.

    Google Scholar 

  167. Ushmaev, A.V. and Petrii, O.A., Elektrokhimiya, 1981, vol. 17, p. 1154.

    Google Scholar 

  168. Kalish, T.V., Petrii, O.A., Ushmaev, A.V., and Voronina, G.F., Elektrokhimiya, 1980, vol. 16, p. 1236.

    CAS  Google Scholar 

  169. Ushmaev, A.V., Voronina, G.F., Kalish, T.V., and Petrii, O.A., Elektrokhimiya, 1982, vol. 18, p. 530.

    CAS  Google Scholar 

  170. Kolics, A. and Wieckowski, A., J. Phys. Chem. B., 2001, vol. 105, p. 2588.

    Article  CAS  Google Scholar 

  171. Funtikov, A.M., Stimming, U., and Vogel, R., J. Electroanal. Chem., 1997, vol. 428, p. 147.

    Article  CAS  Google Scholar 

  172. Hoshi, N., Sakurada, A., Nakamura, S., Teruya, S., Koga, O., and Hori, Y., J. Phys. Chem. B, vol. 106, p. 1985.

  173. Lachenwitzer, A., Li, N., and Lipkowski, J., J. Electroanal. Chem., 2002, vol. 532, p. 85.

    Article  CAS  Google Scholar 

  174. Fromondi, I. and Scherson, D., J. Phys. Chem. C, 2007, vol. 111, p. 10154.

    Article  CAS  Google Scholar 

  175. Braunschweig, B. and Daum, W., Langmuir, 2009, vol. 25, p. 11112.

    Article  CAS  Google Scholar 

  176. Braunschweig, B., Mukherjee, P., Dlott, D.D., and Wieckowski, A., J. Am. Chem. Soc., 2010, vol. 132, p. 14036.

    Article  CAS  Google Scholar 

  177. Voropaeva, T.N., Deryagin, B.V., and Kabanov, B.N., Dokl. Akad. Nauk SSSR, 1959, vol. 128, p. 981.

    Google Scholar 

  178. Plieth, W.J., J. Phys. Chem., 1982, vol. 86, p. 3166.

    Article  CAS  Google Scholar 

  179. Burshtein, R.Kh., Shurmovskaya, N.A., Kalish, T.V., and Larin, L.A., Elektrokhimiya, 1977, vol. 13, p. 799.

    CAS  Google Scholar 

  180. Kotz, E.R., Neff, H., and Muller, K., J. Electroanal. Chem., 1986, vol. 215, p. 331.

    Article  CAS  Google Scholar 

  181. Sass, J.K., Vacuum, 1983, vol. 33, p. 741.

    Article  CAS  Google Scholar 

  182. Sass, J.K., Bange, K., Dohl, R., Piltz, E., and Unwin, R., Ber. Bunsen-Ges. Phys. Chem., 1984, vol. 88, p. 354.

    Article  CAS  Google Scholar 

  183. Wagner, F.T., in Structure of Electrified Interfaces, Lipkowski, J., Ross, P.N., Eds., New York: VCH Publishers, 1993, Ch. 9.

  184. Stuve, E.M. and Kizhakevariam, N., J. Vac. Sci. Technol., A, 1993, vol. 11, p. 2217.

    Article  CAS  Google Scholar 

  185. Weaver, M.J. and Villegas, I., Langmuir, 1997, vol. 13, p. 6836.

    Article  CAS  Google Scholar 

  186. Petrii, O.A., Vasina, S.Ya., and Luk’yanicheva, L.Yu., Elektrokhimiya, 1981, vol. 17, p. 1383.

    CAS  Google Scholar 

  187. Petrii, O.A. and Khomchenko, I.G., Elektrokhimiya, 1977, vol. 13, p. 570.

    CAS  Google Scholar 

  188. Angelucci, C.A., Souza-Garcia, J., Herrero, E., and Feliu, J.M., J. Electroanal. Chem., 2010, vol. 646, p. 100.

    Article  CAS  Google Scholar 

  189. Derry, G.N. and Li-Zhong, Z., Phys.Rev. B (Condensed Matter), 1989, vol. 39, p. 1940.

    Article  CAS  Google Scholar 

  190. Rotemund, H.H., Jabilith, S., Kubala, S., van Oertzen, A., and Ertl, G., J. Electron Spectrosc. Relat. Phenom., 1990, vol. 52, p. 81.

    Google Scholar 

  191. Nieuwenhuys, B.E. and Sachtler, W.M.H., Surf. Sci., 1973, vol. 37, p. 317.

    Article  Google Scholar 

  192. Bertolo, M. and Jacobi, K., Surf. Sci., 1990, vol. 226, p. 207.

    Article  CAS  Google Scholar 

  193. Eichler, A., Hafner, J., and Kresse, G., J. Phys. Condens. Mat., 1976, vol. 8, p. 7659.

    Article  Google Scholar 

  194. Vanselow, R. and Li, X.Q.D., Surf. Sci., 1992, vol. 264, p. L200.

    Article  CAS  Google Scholar 

  195. Frechard, F., van Santen, R.A., Sioku, A., Niemantevordriet, J.W., and Hafner, J., J. Chem. Phys., 1999, vol. 111, p. 8124.

    Article  CAS  Google Scholar 

  196. Castro, G.R., Busse, H., Schneider, U., Janssens, T., and Wandelt, K., Physica Scr., 1992, vol. 41, p. 208.

    Article  Google Scholar 

  197. Nieuwenhuys, B.E., Meijer, D.T., and Sachtler, W.M.H., Surf. Sci., 1973, vol. 40, p. 125.

    Article  CAS  Google Scholar 

  198. Strmnik, D., Kodama, K., van der Vliet, D., Greeley, J., Stamenkovic, V.R., and Markovic, N.M., Nat. Chem., 2009, vol. 1, p. 466.

    Article  CAS  Google Scholar 

  199. Garcia, G., Rodriguez, P., Rosca, V., and Koper, M.T.M., Langmuir, 2009, vol. 25, p. 13661.

    Article  CAS  Google Scholar 

  200. van der Vliet, D.F. and Koper, M.T.M., Surf. Sci., 2010, vol. 604, p. 1912.

    Article  CAS  Google Scholar 

  201. Aran-Ais, R.M., Figueiredo, M.C., Vidal-Iglesias, J., Climent, V., Herrero, E., and Feliu, J.M., Electrochim. Acta, 2011, vol. 58, p. 184.

    Article  CAS  Google Scholar 

  202. Entina, V.S. and Petrii, O.A., Elektrokhimiya, 1968, vol. 4, p. 457.

    CAS  Google Scholar 

  203. Lin, W.F., Christensen, P.A., Hamnett, A., Zei, M.S., and Ertl, G., J. Phys. Chem. B, vol. 104, p. 664.

  204. Marinkovic, N.S., Wang, J.X., Zajonz, H., and Adzic, R.R., J. Electroanal. Chem., 2001, vol. 500, p. 388.

    Article  CAS  Google Scholar 

  205. Ikemiya, N., Suzuki, T., and Ito, M., Surf. Sci., 2000, vol. 466, p. 119.

    Article  CAS  Google Scholar 

  206. Yang, L.Y.O., Yau, S.L., and Itaya, K., Langmuir, 2004, vol. 20, p. 4596.

    Article  CAS  Google Scholar 

  207. El-Aziz, A.M. and Kibler, L.A., Electrochem. Commun., 2002, vol. 4, p. 866.

    Article  CAS  Google Scholar 

  208. Hoster, H., Richter, B., and Behm, R.J., J. Phys. Chem. B, 2004, vol. 108, p. 14780.

    Article  CAS  Google Scholar 

  209. Huxter, S.E. and Attard, G.A., Electrochem.Commun., 2006, vol. 8, p. 1806.

    Article  CAS  Google Scholar 

  210. Bogolowski, N. and Huxter, S., Abd-El-Aziz, A., Abd-El-Latif, Attard, G.A., Baltruschat, H., J. Electroanal. Chem., 2010, vol. 646, p. 68.

    Article  CAS  Google Scholar 

  211. Paffett, M.T., Campbell, C.T., and Taylor, T.N., J. Chem. Phys., 1986, vol. 85, p. 6176.

    Article  CAS  Google Scholar 

  212. Taylor, C.D., Janik, M.J., Neurock, M., and Kelly, R.G., Mol. Simul., 2007, vol. 33, p. 429.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, Russia

    O. A. Petrii

Authors
  1. O. A. Petrii
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. A. Petrii.

Additional information

Original Russian Text © O.A. Petrii, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 5, pp. 451–474.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Petrii, O.A. Zero charge potentials of platinum metals and electron work functions (Review). Russ J Electrochem 49, 401–422 (2013). https://doi.org/10.1134/S1023193513050145

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193513050145

Keywords

Search

Navigation