Abstract
Li8Zr1 − x Ce x O6 solid solutions based on lithium zirconate Li8ZrO6 were obtained by solid-state synthesis in an inert atmosphere. Their transport properties (the electron component of the total conductivity, the temperature and concentration dependences of conductivity, and the activation energies) were studied by impedance spectroscopy. The practical stability of the ceramic samples of Li8Zr1 − x Ce x O6 solid solutions (x = 0–0.07) at 473–573 K against melted lithium was studied.
Similar content being viewed by others
References
Pantyukhina, M.I., Andreev, O.L., Antonov, B.D., and Batalov, N.N., Zh. Neorg. Khim., 2002, vol. 47, no. 11, p. 1778.
JCPDS-ICCD (Joint committee on powder diffraction standards) 2006.
Shannon, R.D., Acta Crystallogr., 1976, vol. A32.
Stoinov, Z.B., Grafov, B.M., Savova-Stoinov, B.S., and Elkin, V.V., in Elektrokhimicheskii impedans (Electrochemical Impedance), Moscow: Nauka, 1991.
Irvine, J.T.S., Sinclair, D.C., and West, A.R., Advanced Materials, 1990, vol. 2, no. 3, p. 132.
Muhle, C., Dinnebier, R.E., Wullen, L., and Schwering, G., Inorg. Chem., 2004, vol. 43, p. 874.
Brice, J.-F. and Ramdani, A., Mater. Res. Bull., 1981, vol. 16, p. 1487.
Pantyukhina, M.I., Shchelkanova, M.S., Stepanov, A.P., and Buzlukov, A.L., Izv. Akad. Nauk, Ser. Fiz., 2010, vol. 74, no. 5, p. 689.
Lyublinskii, I.E., Vertkov, A.V., and Evtikhin, V.A., Vopr. Atom. Nauki i Tekhniki. Termoyadernyi Sintez, 2007, no. 4, p. 13.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.I. Pantyukhina, M.S. Shchelkanova, S.V. Plaksin, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 2, pp. 159–164.
Rights and permissions
About this article
Cite this article
Pantyukhina, M.I., Shchelkanova, M.S. & Plaksin, S.V. Electrochemical properties of solid solutions in the Li8Zr1 − x Ce x O6 system. Russ J Electrochem 49, 144–148 (2013). https://doi.org/10.1134/S1023193513020146
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193513020146