Skip to main content
SpringerLink
Log in

Kinetics of gas-phase oxygen exchange with La0.6Sr0.4MeO3 − δ (Me = Mn, Co)

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The method of isotopic exchange was used to study the kinetics of interaction between the gasphase oxygen and oxides, La0.6Sr0.4MnO3 − δ (LSM) and La0.6Sr0.4CoO3 − δ (LSC), in the temperature range of 600–850°C at the oxygen pressures of 0.13–8.53 kPa. The values of the interphase exchange rate and oxygen diffusion coefficient were determined. Effective activation energies of the oxygen exchange and diffusion processes were 0.71 ± 0.16 and 1.42 ± 0.32 eV for LSM and 0.11 ± 0.03 and 1.08 ± 0.19 eV for LSC, accordingly. The contributions of the three oxygen exchange types were calculated. It was found that the exponent in the dependence of the interphase exchange rate on \(P_{O_2 }\) (n) and the exponent in the dependence of the concentration of oxygen vacancies in the oxide on \(P_{O_2 }\) (ɛ) are related as: n = 1 + ɛ. Fulfillment of this relationship implies participation of the molecular form of oxygen (O2)a on the surface of the studied oxides as the rate-determining stage of exchange.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Fergus, J.W., Hui, R., Li, X., Wilkinson, D.P., and Zhang, J., Solid Oxide Fuel Cells: Materials, Properties, And Performance, CRC Press, 2009, p. 313.

  2. Pal’guev, S.F. and Gil’derman, V.K., Kislorodnyi perenos v oksidnykh elektronnykh provodnikakh (Oxygen Transport in Oxide Electron Conductors), Yekaterinburg: UrO RAN, 2004.

    Google Scholar 

  3. Porotnikova, N.M., Ananyev, M.V., and Kurumchin, E.Kh., Russ. J. Electrochem., 2011, vol. 47, p. 1250.

    Article  CAS  Google Scholar 

  4. Kurumchin, E.Kh., Doctoral (Chem.) Dissertation, Yekaterinburg: IVTE UrO RAN, 1997, p. 195.

    Google Scholar 

  5. Zuev, A.Yu., Petrov, A.N., Vylkov, A.I., and Tsvetkov, D.S., Zh. Fiz. Khim., 2007, vol. 81, no. 1, p. 78.

    Google Scholar 

  6. Kofstad, P., Non-stoichiometry, Diffusion, and Electrical Conductivity in Binary Metal Oxides, New York: Wiley Interscience, 1972.

    Google Scholar 

  7. Poulsen, F.W., Solid State Ionics, 2000, vol. 129, p. 145.

    Article  CAS  Google Scholar 

  8. Mizusaki, J., Mori, N., Takai, H., Yonemura, Y., Minamiue, H., Tagawa, H., Dokiya, M., Inaba, H., Naraya, K., Sasamoto, T., and Hashimoto, T., Solid State Ionics, 2000, vol. 129, p. 163.

    Article  CAS  Google Scholar 

  9. Sogaard, M., Hendriksen, P.V., Mogensen, M., Poulsen, F.W., and Skou, E., Solid State Ionics, 2006, vol. 177, p. 3285.

    Article  CAS  Google Scholar 

  10. Inoue, T., Kamimae, J., Ueda, M., Eguchi, K., and Arai, H., J. Mater. Chem., 1993, vol. 3, p. 751.

    Article  CAS  Google Scholar 

  11. Berenov, A.V., Atkinson, A., Kilner, J.A., Bucher, E., and Sitte, W., Solid State Ionics, 2010, vol. 181, p. 819.

    Article  CAS  Google Scholar 

  12. Ananyev, M.V., Kurumchin, E.Kh., and Porotnikova, N.M., Russ. J. Electrochem., 2010, vol. 46, p. 789.

    Article  CAS  Google Scholar 

  13. Kilner, J.A., De Souza, R.A., and Fullarton, I.C., Solid State Ionics, 1996, vol. 86–88, p. 703.

    Article  Google Scholar 

  14. Ananyev, M.V. and Gavrilyuk, A.L., in Tez. dokl. 41-i Vserossiiskoi molodezhnoi konferentsii “Problemy teoreticheskoi i prikladnoi matematiki” (Abstracts of 41 All-Russia Youth Conference “Problems of Theoretical and Applied Mathematics”), Yekaterinburg: Uchebno-metodicheskii tsentr UPI, 2010, p. 522.

    Google Scholar 

  15. Ananyev, M.V., Svidetel’stvo o gosudarstvennoi registratsii programmy dlya EVM no. 2011614003 (State Registration Certificate of Computer Program no. 2011614003), Russia, 2011.

  16. Klier, K. and Kucera, E., J. Phys. Chem. Solids, 1966, vol. 27, p. 1087.

    Article  CAS  Google Scholar 

  17. Muzykantov, V.S., Panov, G.I., and Boreskov, G.K., Kinet. Katal., 1973, vol. 14, p. 948.

    CAS  Google Scholar 

  18. Ezin, A.N., Tsidilkovski, V.I., and Kurumchin, E.Kh., Solid State Ionics, 1996, vol. 84, p. 105.

    Article  CAS  Google Scholar 

  19. Muzykantov, V.S., Kinet. Katal., 1965, vol. 6, p. 952.

    CAS  Google Scholar 

  20. Boreskov, G.K., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Nauka, 1986, pp. 176–183

    Google Scholar 

  21. Muzykantov, V.S. and Shestov, A.A., in Tez. dokl. IV vsesoyuz. konf. po mekhanizmu kataliticheskikh reaktsii (Abstracts of IV All-Union Conference on Mechanisms of Catalytic Reactions), Moscow: Khimiya, 1986, part 2, p. 391.

    Google Scholar 

  22. Yang, M., Zhong, Y., and Liu, Z.-K., Solid State Ionics, 2007, vol. 178, p. 1027.

    Article  CAS  Google Scholar 

  23. Vinter, E., Kataliz. Issledovanie poverkhnosti katalizatorov (Catalysis, Studies of Catalyst Surface), Moscow: Izd-vo inostr. lit, 1960.

    Google Scholar 

  24. Zakhtler, V.M., in Simp. 4 Mezhdunar. kongr. po katalizu (Symposium of 4 International Congress on Catalysis), Moscow: Nauka, 1970, p. 73.

    Google Scholar 

  25. Shvets, V.A., Vorotyntsev, V.M., and Kazanskii, V.B., Kinet. Katal., 1969, vol. 10, p. 365.

    Google Scholar 

  26. Kazanskii, V.B., Nikitina, O.V., Pariiskii, G.B., and Kiselev, V.F., Dokl. Akad. Nauk SSSR, 1963, vol. 151, no. 2, p. 369.

    CAS  Google Scholar 

  27. Kon’, M.Ya., Shvets, V.A., and Kazanskii, V.B., I Sovetsko-yaponskii seminar po katalizu, Preprint 12 (I Soviet-Japanese Seminar on Catalysis, Preprint 12), 1971.

  28. Van Hoof, J.H.C. and Van Helden, J.F., J. Catal., 1967, vol. 8, p. 100.

    Article  Google Scholar 

  29. Pilania, G. and Ramprasad, R., Surf. Sci., 2010, vol. 604, p. 1889.

    Article  CAS  Google Scholar 

  30. Wahab, H.S., Bredow, T., and Aliwi, S.M., J. Mol. Struct.: THEOCHEM, 2008, vol. 868, p. 101.

    Article  CAS  Google Scholar 

  31. Zhou, J., Chen, G., Wu, K., Cheng, Y., Peng, B., Guo, J., and Jiang, Y., Appl. Surf. Sci., 2012, vol. 268, p. 3133.

    Article  Google Scholar 

  32. Ozaki, A., Isotopic Studies of Heterogeneous Catalysis, Academic Press Inc., 1978.

  33. Panov, G.I., Boreskov, G.K., and Kharitonov, A.S., Kinet. Katal., 1982, vol. 22, p. 438.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620990, Russia

    N. M. Bershitskaya, M. V. Ananyev, E. Kh. Kurumchin & V. A. Eremin

Authors
  1. N. M. Bershitskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. V. Ananyev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Kh. Kurumchin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Eremin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. M. Bershitskaya.

Additional information

Original Russian Text © N.M. Bershitskaya, M.V. Ananyev, E.Kh. Kurumchin, V.A. Eremin, 2012, published in Elektrokhimiya, 2012, Vol. 48, No. 10, pp. 1057–1065.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bershitskaya, N.M., Ananyev, M.V., Kurumchin, E.K. et al. Kinetics of gas-phase oxygen exchange with La0.6Sr0.4MeO3 − δ (Me = Mn, Co). Russ J Electrochem 48, 961–968 (2012). https://doi.org/10.1134/S1023193512100059

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193512100059

Keywords

Search

Navigation