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The experimental verification of mathematical two-plate model describing the metal deposition/dissolution process

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Abstract

The advanced two-plate model with BET adsorption equation has been verified by the use of the experimental Cu2+/Cu0 system in 1 M NaClO4/pH 3 solution at different scan rates and at 5, 10, 25 mM concentrations of Cu2+. A change of electrode properties during electrode process was included into the applied model. The model reflects a characteristic loop on cathodic part of CV response. The values of elementary kinetic parameters have been determined and discussed.

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Authors and Affiliations

  1. Faculty of Chemistry, Rzeszów University of Technology, Powstanców Warszawy Str. 12, 35-959, Rzeszów, Poland

    Piotr M. Skitał & Przemysław T. Sanecki

Authors
  1. Piotr M. Skitał
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  2. Przemysław T. Sanecki
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Corresponding author

Correspondence to Przemysław T. Sanecki.

Additional information

Published in Russian in Elektrokhimiya, 2012, Vol. 48, No. 8, pp. 876–883.

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Skitał, P.M., Sanecki, P.T. The experimental verification of mathematical two-plate model describing the metal deposition/dissolution process. Russ J Electrochem 48, 797–803 (2012). https://doi.org/10.1134/S1023193512070105

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  • DOI: https://doi.org/10.1134/S1023193512070105

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