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Studies of asymmetry of diffusion permeability of nanocomposite ion-exchange membranes: Model of charge density of fixed groups linear by membrane thickness

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Abstract

A new model of a fine-porous membrane with a linear distribution of charges of its fixed groups along its depth is suggested in the work to explain the effect of asymmetry of diffusion permeability of perfluorinated MF-4SK membranes surface-modified by polyaniline. The model allowed better describing the experimental data for the synthesized nanocomposite MF-4SK/PANI membranes than the earlier developed model of a bilayer membrane with constant fixed charge densities in layers, which points to its feasilibity.

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Correspondence to A. N. Filippov.

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Original Russian Text © A.N. Filippov, R.Kh. Iksanov, 2012, published in Elektrokhimiya, 2012, Vol. 48, No. 2, pp. 200–207.

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Filippov, A.N., Iksanov, R.K. Studies of asymmetry of diffusion permeability of nanocomposite ion-exchange membranes: Model of charge density of fixed groups linear by membrane thickness. Russ J Electrochem 48, 181–188 (2012). https://doi.org/10.1134/S1023193512020036

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  • DOI: https://doi.org/10.1134/S1023193512020036

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