Skip to main content
SpringerLink
Log in

Thermodynamic study of Cu-Tl-Te system using EMF technique with Cu4RbCl3I2 solid electrolyte

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The EMF method with a solid Cu+-conducting electrolyte of Cu4RbCl3I2 was sued to study the Cu-Tl-Te system in the temperature range of 300–420 K. A diagram of solid-phase equilibriums of this system is constructed, partial molar functions of copper in alloys, standard thermodynamic functions of formation and standard entropies of CuTlTe2, CuTl4Te3, Cu2TlTe2, Cu3TlTe2, Cu9TlTe5 triple compounds and Cu x Tl5 − x Te3 solid solutions (0 < x < 1) are calculated. The obtained results confirmed the assumption as to the possibility of using this modification for the EMF technique for thermodynamic studies of copper-containing triple systems, even if they contain a less noble component than copper.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Gurevich, Yu.Ya. and Kharkats, Yu.I., Superionnye provodniki (Superionic Conductorts), Moscow, 1992.

  2. Ivanov-Shchits, A.K. and Murin, I.V., Ionika tverdogo tela (Ionics of Solids), Izd-vo SPbGU, 2000, vol. 1.

  3. Scholtens, B.B. and Gool, W., in Solid electrolytes, Hagenmuller, P. and Van Goll, W., Eds., New York, San Francisco, London: Acad. Press, 1978, p. 451.

    Google Scholar 

  4. Babanly, M.B., Yusibov, Yu.A., and Abishev, V.T., Metod EDS v termodinamike slozhnykh poluprovodnikovykh veshchestv (EMF Method in Thermodynamics of Complex Semiconductor Compounds), Baku: Izd-vo BGU, 1992.

    Google Scholar 

  5. Babanly, M.B., Yusibov, Yu.A., and Abishev, V.T., Trekhkomponentnye khal’kogenidy na osnove medi i serebra (Three-Component Chalcogenides Based on Copper and Silver), Baku: Izd-vo BGU, 1993.

    Google Scholar 

  6. Mustafaev, F.M., Abbasov, A.S., and Aliev, I.Ya., in Tverdye elektrolity i ikh analiticheskoe primenenie (Solid Electrolytes and Their Analytical Application), Minsk: Universitetskoe, 1990, p. 96.

    Google Scholar 

  7. Babanly, M.B., Yusibov, Yu.A., and Babanly, N.B., Vestn. BGU, Ser. Estestv. Nauk, 1999, no. 4, p. 21.

  8. Babanly, M.B., Guseinov, Z.A., Guseinov, F.N., Mekhiyev, I.S., and Abbasov, A.A., VI International School-Conference “Phase Diagrams in Material Science” (PDMS VI-2001), Kiev, 2001, p. 4.

  9. Babanly, N.B., Yusibov, Yu.A., Mirzoeva, R.Dzh., Shykhyev, Yu.M., and Babanly, M.B., Russ. J. Electrochem., 2009, vol. 45, no. 4, p. 405.

    Article  CAS  Google Scholar 

  10. Babanly, N.B., Yusibov, Yu.A., Aliev, Z.S., and Babanly, M.B., Zh. Neorg. Khim., 2010, vol. 55, no. 9, p. 1557.

    Google Scholar 

  11. Babanly, N.B., Aliev, Z.S., Yusibov, Yu.A., and Babanly, M.B., Russ. J. Electrochem., 2010, vol. 46, p. 354.

    Article  CAS  Google Scholar 

  12. Kovaleva, I.S., Kranchevich, K.S., and Nikol’skaya, G.F., Izv. Akad. Nauk SSSR, Neorg. Mater., 1971, vol. 7, no. 5, p. 865.

    CAS  Google Scholar 

  13. Stepenkov, E.I., Nikol’skaya, G.F., Luzhnaya, N.P., and Novikova, A.N., Zh. Neorg. Khim., 1970, vol. 15, no. 7, p. 1959.

    CAS  Google Scholar 

  14. Satow, T., Ishikawa, H., and Uemura, O., Phys. Status Solidi B, 1987, vol. 146, p. 661.

    Article  Google Scholar 

  15. Uemura, O., Wada, Y., Takahara, T., and Satow, T., Phys. Status Solidi B, 1983, vol. 120, p. 685.

    Article  CAS  Google Scholar 

  16. Kurosaki, K., Goto, K., Kosuga, A., and Yamanaka, S., Mater. Trans., 2006, vol. 47, no. 6, p. 1432.

    Article  CAS  Google Scholar 

  17. Matsumoto, H., Kurosaki, K., Muta, H., and Yamanaka, S., J. Electr. Mat., 2009, vol. 38, no. 7, p. 1350.

    Article  CAS  Google Scholar 

  18. Binary Alloy Phase Diagrams, ASM Intern. Materials Park, Massalski, T.B., ed., Ohio, 1990, vol. 2.

  19. Kleep, K.O., J. Less-Common. Met., 1987, vol. 127, p. 79.

    Article  Google Scholar 

  20. Tedenac, J.-C., Brun, G., Lardes, B., et al., C. R. Acad. Sci., C., 1976, vol. 283, no. 12, p. 529.

    Google Scholar 

  21. Bradtmöller, S. and Böttcher, P., Z. Kristallogr., 1994, vol. 209, p. 97.

    Article  Google Scholar 

  22. Morachevskii, A.G., Voronin, G.F., Geiderikh, V.A., and Kutsenok, I.B., Elektrokhimicheskie metody issledovaniya v termodinamike metallicheskikh sistem (Electrochemical Research Methods in Thermodynamics of Metallic Systems), Moscow: Akademkniga, 2003.

    Google Scholar 

  23. Cerny, R., Joubert, J., Filinchuk, Y., and Feutelais, Y., Acta. Crystallogr., vol. 58, no. 5, p. 163.

  24. Asadov, M.M., Babanly, M.B., and Kuliev, A.A., Izv. Akad. Nauk SSSR, Neorg. Mater., 1977, vol. 13, no. 8, p. 1407.

    CAS  Google Scholar 

  25. Record, M.C., Feutelais, Y., and Lukas, H.L., Z. Metalkd., 1997, vol. 88, p. 45.

    CAS  Google Scholar 

  26. Doerffel, K., Statistik in der analytischen Chemie, Verlag Chemie, 1984, 3 ed.

  27. Kornilov, A.N., Stepina, L.B., and Sokolov, V.A., Zh. Fiz. Khim., 1972, vol. 46, no. 11, p. 2974.

    Google Scholar 

  28. Man, L.I., Imamov, R.M., and Pinsker, Z.G., Kristallografiya, 1971, vol. 16, no. 1, p. 122.

    CAS  Google Scholar 

  29. Imamalieva, S.Z., Sadygov, F.M., and Babanly, M.B., Neorgan. Mater., 2008, vol. 44, no. 9, p. 1054.

    Google Scholar 

  30. Babanly, M.B. and Kuliev, A.A., in Matematicheskie zadachi khimicheskoi termodinamiki (Mathematical Problems of Chemical Thermodynamics), Novosibirsk: Nauka, 1985, p. 192.

    Google Scholar 

  31. Vasil’ev, V.P., Nikol’skaya, A.V., Chernyshev, V.V., and Gerasimov, Ya.I., Izv. Akad. Nauk SSSR, Neorg. Mater., 1973, vol. 9, no. 6, p. 900.

    Google Scholar 

  32. Azizov, T.Kh., Aliev, I.Ya., Mustafaev, F.M., and Abbasov, A.S., in Termodinamicheskie svoistva tverdykh metallicheskikh splavov (Thermodynamic Properties of Solid Metallic Alloys), Minsk: Izd-vo BGU, 1976, p. 86.

    Google Scholar 

  33. Baza dannykh termicheskikh konstant veshchestv. Elektronnaya versiya (Database of Thermal Constants of Compounds. Electronic Version), Yungman, V.S., Ed., 2006, http://www.chem.msu.su/cgi-bin/tkv.

  34. Babanly, M.B., Salimov, Z.E., Babanly, N.B., and Imamalieva, S.Z., Neorgan. Mater., 2011, vol. 47, p. 415.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Problems, Azerbaijan National Academy of Sciences, G. Dzhavida pr. 29, Baku, AZ 114, Azerbaijan

    N. B. Babanly & M. M. Akhmedov

  2. Azerbaijan Technical University, G. Dzhavida pr. 25, Baku, AZ 1073, Azerbaijan

    Z. E. Salimov

  3. Baku State University, ul. Z. Khalilova 23, Baku, AZ 1148, Azerbaijan

    M. B. Babanly

Authors
  1. N. B. Babanly
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. E. Salimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. M. Akhmedov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. B. Babanly
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. B. Babanly.

Additional information

Original Russian Text © N.B. Babanly, Z.E. Salimov, M.M. Akhmedov, M.B. Babanly, 2012, published in Elektrokhimiya, 2012, Vol. 48, No. 1, pp. 76–81.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Babanly, N.B., Salimov, Z.E., Akhmedov, M.M. et al. Thermodynamic study of Cu-Tl-Te system using EMF technique with Cu4RbCl3I2 solid electrolyte. Russ J Electrochem 48, 68–73 (2012). https://doi.org/10.1134/S1023193512010041

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193512010041

Keywords

Search

Navigation