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Topokinetic model of active dissolution of a solid electrode with point lattice defects. analysis and comparison of the results obtained in solving equations with the experimental data

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Abstract

A model that takes into account the consistence between the atomic relief with the metal dissolution (corrosion) rate and also considers the direct effect of point lattice defects (vacancies or atoms of impurities with the corrosion resistance far deviating from that of the base metal) on this consistence is compared with experimental data. Despite the substantial simplifications taken in this model, the latter makes it possible to explain the main manifestations of effect of defects on the metal dissolution rate.

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Authors and Affiliations

  1. Karpov Institute of Physical Chemistry, Votontsovo Pole 10, Moscow, 103064, Russia

    Yu. V. Alekseev & A. V. Plaskeev

  2. Joint Institute of High Temperatures, Russian Academy of Sciences, Izhorskaya ul. 13, Moscow, 125412, Russia

    Yu. V. Alekseev

  3. Research Institute of Precise Instruments, Moscow, Russia

    I. Yu. Alekseev

Authors
  1. Yu. V. Alekseev
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  2. A. V. Plaskeev
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  3. I. Yu. Alekseev
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Correspondence to Yu. V. Alekseev.

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Original Russian Text © Yu.V. Alekseev, A.V. Plaskeev, I.Yu. Alekseev, 2012, published in Elektrokhimiya, 2012, Vol. 48, No. 1, pp. 64–75.

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Alekseev, Y.V., Plaskeev, A.V. & Alekseev, I.Y. Topokinetic model of active dissolution of a solid electrode with point lattice defects. analysis and comparison of the results obtained in solving equations with the experimental data. Russ J Electrochem 48, 57–67 (2012). https://doi.org/10.1134/S102319351201003X

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  • DOI: https://doi.org/10.1134/S102319351201003X

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