Abstract
In this work, the routes of the redox reactions of chalcogenbiscyclanones and the products of their S-, O-, N-heterocyclization in organic solvents were analyzed and validated. The influence of the nature of the heteroatoms and substituents on the redox activity of S- and Se-containing biscyclanones, benzannelated thianthrenes, oxathianthrenes, and diazepine was established based on electrochemical studies, ESR spectroscopy data, and the results of quantum chemical calculations
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Original Russian Text © E.V. Shinkar’, O.V. Fedotova, K.P. Pashchenko, Ya.B. Aref’ev, N.T. Berberova, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 10, pp. 1254–1261.
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Shinkar’, E.V., Fedotova, O.V., Pashchenko, K.P. et al. Electrochemical reactions of chalcogenbiscyclanones and the products of their S-, O-, and N-heterocyclization. Russ J Electrochem 47, 1172–1179 (2011). https://doi.org/10.1134/S1023193511100193
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DOI: https://doi.org/10.1134/S1023193511100193