Abstract
Effects of interference of the adsorption of cations and anions located in different layers of the electrical double layer dense part (under the conditions of linear dependence of their adsorption energy on the electrode charge) analyzed in the context of a system comprising two Frumkin mixed isotherms. The model was shown to suit for the explaining of the retraction of weakly adsorbed cations into the dense layer in the case of practical independence of the total surface excess of the cations on their localizing plane in the electrical double layer. The effect of co-adsorption of cations and anions in such systems on the total differential capacitance of electrode is analyzed.
Similar content being viewed by others
References
Damaskin, B.B., Elektrokhimiya, 2011, vol. 47, p. 259 [Russ. J. Electrochem. (Engl. Transl.), vol. 47, p.].
Damaskin, B.B., Safonov, V.A., and Safonov, N.V., Elektrokhimiya, 2004, vol. 40, p. 899. [Damaskin V.V., Safonov V.A., and Safonof N.V., Russ. J. Electrochem., 2004, vol. 40, p. 781.]
Grahame, D.C., Chem. Rev., 1947, vol. 41, p. 447.
Rogozhnikov, N.A., Elektrokhimiya, 2002, vol. 38, p. 1386. [Rogozhnikov, N.A., Russ. J. Electrochem., 2002, vol. 38.]
Sanz, F. and Gonzalez, R., Electrochim. Acta, 1989, vol. 34, p. 1883.
Damaskin, B.B., Elektrokhimiya, 2010, vol. 46, p. 1160. [Damaskin B.B., Russ. J. Electrochem., 2010, vol. 46, p. 1086.]
Damaskin, B.B., Praktikum po elektrokhimii (Laboratory Course in Electrochemistry), Damaskin, B.B., Ed., Moscow: Vyssh. Shkola, 1991.
Payne, R., Trans. Faraday Soc., 1968, vol. 64, p. 1638.
Lyklema, J. and Parsons, R., Electrical Properties of Interfaces. Compilation of Data on the Electrical Double Layer on Mercury, Washington, DC: National Bureau of Standards, 1983.
Grahame, D.C. and Parsons, R., J. Am. Chem. Soc., 1961, vol. 83, p. 1291.
Ivanova, R.V., Damaskin, B.B., and Mazurek, S., Elektrokhimiya, 1970, vol. 6, p. 1041.
Damaskin, B.B., J. Electroanal. Chem., 1975, vol. 65, p. 799.
Damaskin, B.B. and Baturina, O.A., Elektrokhimiya, 1999, vol. 35, p. 1343. [Russ. J. Electrochem., 1999, vol. 35, p. 118.]
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © B.B. Damaskin, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 9, pp. 1058–1065.
Rights and permissions
About this article
Cite this article
Damaskin, B.B. Modeling of co-adsorption of cations and anions localized in different layers of the dense part of electrical double layer under the conditions of linear charge dependence of the adsorption energy. Russ J Electrochem 47, 988–994 (2011). https://doi.org/10.1134/S1023193511090047
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193511090047