Skip to main content
SpringerLink
Log in

Preparation and characterization of LiMn2O4/Li1.3Al0.3Ti1.7(PO4)3/LiMn2O4 thin-film battery by spray technique

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Solid-state thin-film lithium-ion battery of LiMn2O4/Li1.3Al0.3Ti1.7(PO4)3/LiMn2O4 is prepared by spray technique using Li1.3Al0.3Ti1.7(PO4)3 sintered pellet as both electrolyte and substrate. The thin-film battery is heat-treated by rapid thermal annealing. Phase identification, morphology and electrochemical properties of the sintered pellets and thin-film battery are investigated by X-ray diffraction, scanning electron microscopy, electrochemical impedance spectroscopy, cyclic voltammetry, and galvanostatic charge-discharge experiments, respectively. The results show that LiMn2O4 films with some pores are well deposited on the surface of Li1.3Al0.3Ti1.7(PO4)3 sintered pellet. The discharge current density and temperature have considerable effect on discharge capacity of the thin-film battery. LiMn2O4/Li1.3Al0.3Ti1.7(PO4)3/LiMn2O4 thin-film battery can be easily cycled with a capacity loss of 0.213% per cycle when 50 cycles are carried out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hayashi, M., Takahashi, M., and Sakurai, Y., J. Power Sources, 2007, vol. 174, p. 990.

    Article  CAS  Google Scholar 

  2. Lee, T., Cho, K., Oh, J., and Shin, D., J. Power Sources, 2007, vol. 174, p. 394.

    Article  CAS  Google Scholar 

  3. Bates, J.B., Dudney, N.J., Neudecker, B., Ueda, A., and Evans, C.D., Solid State Ionics, 2000, vol. 35, p. 33.

    Article  Google Scholar 

  4. Baskaran, R., Kuwata, N., and Kamishima, O., Solid State Ionics, 2009, vol. 180, p. 636.

    Article  CAS  Google Scholar 

  5. Kim, J.M., Park, G.B., and Lee, K.C., J. Power Sources, 2009, vol. 189, p. 211.

    Article  CAS  Google Scholar 

  6. Pan, H. and Yang, Y., J. Power Sources, 2009, vol. 189, p.633.

  7. Subramania, A., Karthick, S.N., and Angayarkanni, N., Thin Solid Films, 2008, vol. 516, p. 8295.

    Article  CAS  Google Scholar 

  8. Cho, K., Lee, T., and Oh, J., Solid State Ionics, 2007, vol. 178, p. 119.

    Article  CAS  Google Scholar 

  9. Xia, H., Tang, S.B., Lu, L., Meng, Y.S., and Ceder, G., Electrochim. Acta, 2007, vol. 52, p. 2822.

    Article  CAS  Google Scholar 

  10. Yu, X., Bates, J.B., Jellison, G.E., and Hart, F.X., J. Electrochem. Soc, 1997, vol. 144, p. 524.

    Article  CAS  Google Scholar 

  11. Aono, H., Sugimoto, E., Sadaoka, Y., Imanaka, N., and Adachi, G., J. Electrochem. Sec, 1989, vol. 136, p. L590.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Jishou University, Jishou Hunan, 416000, China

    Xian Ming Wu, Jin Lian Liu, Run Xiu Li, Shang Chen & Ming You Ma

  2. Xiangxi Ores and New Materials Research and Service Center, Jishou Hunan, 416000, China

    Xian Ming Wu & Shang Chen

Authors
  1. Xian Ming Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jin Lian Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Run Xiu Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shang Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ming You Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xian Ming Wu.

Additional information

Published in Russian in Elektrokhimiya, 2011, Vol. 47, No. 8, pp. 980–985.

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wu, X.M., Liu, J.L., Li, R.X. et al. Preparation and characterization of LiMn2O4/Li1.3Al0.3Ti1.7(PO4)3/LiMn2O4 thin-film battery by spray technique. Russ J Electrochem 47, 917–922 (2011). https://doi.org/10.1134/S1023193511080179

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193511080179

Keywords

Search

Navigation