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Electrical properties of crystalline borates

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Abstract

Anisotropy of electrical and dielectric properties of α- and β-BaB2O4, Ba2Na3(B3O6)2F, LiB3O5, and CsLi(B3O5)2 single crystals is reported and discussed. In these crystals, alkali ions are dominant charge carriers; pre-heating to 300°C eliminates the humidity, preheating to 500 or 600°C, stabilizes the structure and electrical properties of crystals. Then, both ionic conductivity and dielectric response are determined by movement of alkali ions, and temperature dependences of the ionic conductivity and static permittivity are well reproducible.

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Authors and Affiliations

  1. Faculty of Education, Catholic University, 03402, Ružomberok, Slovakia

    V. Trnovcová

  2. Faculty of Materials Science and Technology, Slovak University of Technology, 917 24, Trnava, Slovakia

    V. Trnovcová & M. Kubliha

  3. Institute of Mineralogy and Petrography, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. Kokh

  4. Institute of General Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    P. P. Fedorov

  5. Institute of Crystallography, Russian Academy of Sciences, Moscow, 119991, Russia

    R. M. Zakalyukin

Authors
  1. V. Trnovcová
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  2. M. Kubliha
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  3. A. Kokh
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  4. P. P. Fedorov
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  5. R. M. Zakalyukin
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Corresponding author

Correspondence to V. Trnovcová.

Additional information

Published in Russian in Elektrokhimiya, 2011, Vol. 47, No. 5, pp. 568–574.

Published on the basis of a presentation delivered in the Xth Conference “Fundamental Problems of Solid-State Ionics”, Chernogolovka, 2010.

The article is published in the original.

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Trnovcová, V., Kubliha, M., Kokh, A. et al. Electrical properties of crystalline borates. Russ J Electrochem 47, 531–536 (2011). https://doi.org/10.1134/S1023193511050156

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  • DOI: https://doi.org/10.1134/S1023193511050156

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