Skip to main content
SpringerLink
Log in

Transport and thermal characteristics of Cs1 − x Rb x H2PO4

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The transport and thermal properties of Cs1 − x Rb x H2PO4 in a wide range of compositions were studied. The binary salts Cs1 − x Rb x H2PO4 (x = 0–0.9) contain solid solutions with a structure of CsH2PO4. The binary salts were synthesized by mechanically mixing the starting components and growing crystals by isothermal evaporation from aqueous solutions. The properties of Cs1 − x Rb x H2PO4 salts obtained by different procedures were found to differ considerably. At higher rubidium contents in compounds obtained by mechanical mixing, the superionic transition temperature rose insignificantly, the high-temperature phase conductivity decreased twofold, the low-temperature conductivity increased within the limits of the order of magnitude, and the system of hydrogen bonds was slightly weakened. In Cs1 − x Rb x H2PO4 crystals grown from solutions, the temperature of the superionic transition decreased along with its slowing down, and the low-temperature conductivity increased by more than three orders of magnitude because of the higher contents of residual acid aqueous centers in the structure of the salt. These systems are characterized by increased thermal stability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Boysen, D.A., Uda, T., Chisholm, C.R.I., and Haile, S.M., Science, 2004, vol. 303, p. 68.

    Article  CAS  Google Scholar 

  2. Uda, T. and Haile, S.M., Electrochem. Solid State Lett., 2005, vol. 8, no. 5, p. A245.

    Article  CAS  Google Scholar 

  3. Baranov, A.I., Kniznichenko, V.P., Sandler, V.A., and Shuvalov, L.A., Ferroelectrics, 1988, vol. 81, p. 183.

    Article  Google Scholar 

  4. Boysen, D.A. and Haile, S.M., Chem. Mater., 2003, vol. 15, p. 727.

    Article  CAS  Google Scholar 

  5. Baranov, A.I., Grebenev, V.V., Khodan, A.N., Dolbinina, V.V., and Efremova, E.P., Solid State Ionics, 2005, vol. 176, p. 2871.

    Article  CAS  Google Scholar 

  6. Mhiri, T. and Colomban, Ph., Solid State Ionics, 1991, vol. 44, p. 215.

    Article  CAS  Google Scholar 

  7. Chisholm, C.R.I. and Haile, S.M., Solid State Ionics, 2000, vols. 136–137, p. 229.

    Article  Google Scholar 

  8. Tadanaga, K., Yamashita, Y., Hayashi, A., and Tatsumisago, M., Solid State Ionics, 2010, vol. 181, p. 187.

    Article  CAS  Google Scholar 

  9. Sugahara, T., Hayashi, A., Tadanaga, K., and Tatsumisago, M., Solid State Ionics, 2010, vol. 181, p. 190.

    Article  CAS  Google Scholar 

  10. Haile, S.M., Lentz, G., Kreuer, K.-D., and Maier, J., Solid State Ionics, 1995, vol. 77, p. 128.

    Article  CAS  Google Scholar 

  11. Haile, S.M. and Calkins, P.M., J. Solid State Chem., 1998, vol. 140, p. 251.

    Article  CAS  Google Scholar 

  12. Lavrova, V.G., Martsinkevich, V.V., and Ponomareva, V.G., Neorg. Mater., 2009, vol. 45.

  13. Martsinkevich, V.V., Ponomareva, V.G., Drebushchak, T.N., Lavrova, G.V., and Shatskaya, S.S., Neorg. Mater., 2010.

  14. Stolyarova, I.A. and Filatova, M.F., Atomno-adsorbtsionnaya spektrometriya (Atomic Adsorption Spectrometry), Leningrad: Nedra, 1981.

    Google Scholar 

  15. Ognina, V.A., Metody khimicheskogo analiza fosfatnykh rud, Morkovska, G.A., Ed., Moscow: Goskhimizdat, 1961.

    Google Scholar 

  16. Louie, M.W., Kislitsyn, M., Bhattacharya, K., and Haile, S.M., Solid State Ionics, 2010, vol. 181, p. 173.

    Article  CAS  Google Scholar 

  17. Naili, H., Mhiri, T., and Daoud, A., Phase Transitions, 2000, vol. 71, p. 271.

    Article  CAS  Google Scholar 

  18. Atlas IK-spektrov fosfatov (ortofosfatov) (Atlas of IR Spectra of Phosphates (Orthophosphates)), Moscow: Nauka, 1981.

  19. Marchon, B. and Novak, A., J. Chem. Phys., 1983, vol. 78, no. 5, p. 2105.

    Article  CAS  Google Scholar 

  20. Baranov, A.I., Khiznichenko, V.P., and Shuvalov, L.A., Ferroelectrics, 1989, vol. 100, p. 135.

    Article  CAS  Google Scholar 

  21. Metcalfe, B. and Clark, J.B., Thermochim. Acta, 1978, vol. 24, p. 149.

    Article  CAS  Google Scholar 

  22. Baranov, A.I., Dolbinina, V.V., Lancerose-Mendez, S., and Schmidt, V.H.S., Ferroelectrics, 2002, vol. 272, p. 2217.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. G. Ponomareva & V. V. Martsinkevich

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. A. Chesalov

Authors
  1. V. G. Ponomareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Martsinkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Chesalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. G. Ponomareva.

Additional information

Original Russian Text © V.G. Ponomareva, V.V. Martsinkevich, Yu.A. Chesalov, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 5, pp. 645–653.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ponomareva, V.G., Martsinkevich, V.V. & Chesalov, Y.A. Transport and thermal characteristics of Cs1 − x Rb x H2PO4 . Russ J Electrochem 47, 605–612 (2011). https://doi.org/10.1134/S1023193511050090

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193511050090

Keywords

Search

Navigation