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Structure and hydration processes in perfluorinated bilayer cation-exchange membranes

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Abstract

Based on perfluorinated polymers MF-4SK and F-4KF bilayer composite ion-exchange membranes are studied by using the magic-angle-rotation NMR, electrochemical impedance spectroscopy, scanning electron microscopy, and electron-probe microanalysis. It is shown that the contact of the polymers includes an interlayer, approximately 5 μm thick. The NMR data point to slow water-molecules-exchange between hydrate-complexes of sulfo- and carboxyl-groups.

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Authors and Affiliations

  1. Moscow Institute of Physics and Technology, Institutskii proezd 9, Dolgoprudnyi, Moscow oblast, 141700, Russia

    S. L. Shestakov, E. V. Korostylev & A. V. Maksimychev

  2. OAO Plastpolymer, St. Petersburg, Russia

    S. V. Timofeev

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. akad. Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    S. G. Vasil’ev, E. A. Sanginov, Yu. A. Dobrovol’skii & V. I. Volkov

Authors
  1. S. L. Shestakov
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  2. E. V. Korostylev
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  3. S. V. Timofeev
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  4. A. V. Maksimychev
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  5. S. G. Vasil’ev
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  6. E. A. Sanginov
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  7. Yu. A. Dobrovol’skii
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  8. V. I. Volkov
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Corresponding author

Correspondence to S. L. Shestakov.

Additional information

Original Russian Text © S.L. Shestakov, E.V. Korostylev, S.V. Timofeev, A.V. Maksimychev, S.G. Vasil’ev, E.A. Sanginov, Yu.A. Dobrovol’skii, V.I. Volkov, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 4, pp. 420–428.

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Shestakov, S.L., Korostylev, E.V., Timofeev, S.V. et al. Structure and hydration processes in perfluorinated bilayer cation-exchange membranes. Russ J Electrochem 47, 395–403 (2011). https://doi.org/10.1134/S102319351104015X

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  • DOI: https://doi.org/10.1134/S102319351104015X

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