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Ionic conductivity of bismuth oxofluoride BiO0.1F2.8 with tysonite-type structure (LaF3)

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Abstract

The complex impedance method in the temperature range of 291–660 K was used to study conductivity of oxofluoride BiO0.1F2.8 belonging to the tysonite structural type (LaF3). Bismuth oxofluoride was synthesized using a solid-phase method at 770–870 K for 1–2 h in an argon atmosphere. Heterovalent substitution of fluoride ions F− by oxygen ions O2− in the anionic BiF3 matrix sublattice results in high ionic conductivity (∼0.1 S/cm at 660 K) of BiO0.1F2.8 ceramic samples.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russia

    N. I. Sorokin & B. P. Sobolev

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  1. N. I. Sorokin
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  2. B. P. Sobolev
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Correspondence to N. I. Sorokin.

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Original Russian Text © N.I. Sorokin, B.P. Sobolev, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 1, pp. 118–120.

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Sorokin, N.I., Sobolev, B.P. Ionic conductivity of bismuth oxofluoride BiO0.1F2.8 with tysonite-type structure (LaF3). Russ J Electrochem 47, 111–113 (2011). https://doi.org/10.1134/S1023193511010150

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  • DOI: https://doi.org/10.1134/S1023193511010150

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