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Corrections for volume changes in describing diffusion in electrolyte solutions

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Abstract

It is possible to avoid certain difficulties in describing the diffusion in electrolyte solutions by taking into account the process of spatial rearrangement of species that accompanied the concentration variations and was recently introduced into consideration. The experimental substantiation of taking into account this process is the different concentrations of solvent, i.e., water, observed in solutions of different concentrations.

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Authors and Affiliations

  1. Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya 26, St. Petersburg, 194021, Russia

    A. I. Gorshkov

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  1. A. I. Gorshkov
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Correspondence to A. I. Gorshkov.

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Original Russian Text © A.I. Gorshkov, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 1, pp. 113–117.

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Gorshkov, A.I. Corrections for volume changes in describing diffusion in electrolyte solutions. Russ J Electrochem 47, 106–110 (2011). https://doi.org/10.1134/S1023193511010095

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  • DOI: https://doi.org/10.1134/S1023193511010095

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