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Electrochemical oxidation of 1,1-dihydroxy-4-methylcyclohexane on platinum anode. Synthesis of 3,12-dimethyl-7,8,15,16-tetraoxadispiro[5.2.5.2]hexadecane

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Abstract

The possibility is shown of electrochemical synthesis of 3,12-dimethyl-7,8,15,16-tetraoxadispiro[5.2.5.2]hexadecane that belong to the class of 1,2,4,5-tetraoxanes by oxidation of 1,1-dihydroperoxy-4-methylcyclohexane using a Pt anode.

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia

    M. D. Vedenyapina, A. O. Terent’ev, M. M. Platonov, A. A. Vedenyapin & G. I. Nikishin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. M. Skundin

Authors
  1. M. D. Vedenyapina
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  2. A. O. Terent’ev
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  3. M. M. Platonov
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  4. A. M. Skundin
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  5. A. A. Vedenyapin
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  6. G. I. Nikishin
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Correspondence to M. D. Vedenyapina.

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Original Russian Text © M.D. Vedenyapina, A.O. Terent’ev, M.M. Platonov, A.M. Skundin, A.A. Vedenyapin, G.I. Nikishin, 2011, published in Elektrokhimiya, 2011, Vol. 47, No. 2, pp. 251–254.

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Vedenyapina, M.D., Terent’ev, A.O., Platonov, M.M. et al. Electrochemical oxidation of 1,1-dihydroxy-4-methylcyclohexane on platinum anode. Synthesis of 3,12-dimethyl-7,8,15,16-tetraoxadispiro[5.2.5.2]hexadecane. Russ J Electrochem 47, 234–237 (2011). https://doi.org/10.1134/S102319351012102X

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  • DOI: https://doi.org/10.1134/S102319351012102X

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