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Voltammetric determination of D-penicillamine based on its homogeneous electrocatalytic oxidation with potassium iodide at the surface of glassy carbon electrode

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Abstract

The electrooxidation of D-penicillamine (D-PA) has been studied in the presence of potassium iodide in various buffered aqueous solutions (4.00 ≤ pH ≤ 9.00) at the surface of glassy carbon electrode using cyclic voltammetry, differential pulse voltammetry and chronoamperometry. It has been found that under optimum pH (pH 5.00) in cyclic voltammetry, the electrooxidation of D-PA in the presence of potassium iodide as a homogeneous mediator occurred at a potential about 220 mV less positive than that in absence of potassium iodide at the surface of glassy carbon electrode. The homogeneous electrocatalytic oxidation current wave of D-penicillamine was linearly dependent on the D-PA concentration and a linear calibration curve was obtained in the ranges 3.0 × 10−5−1.5 × 10−3 M and 9.0 × 10−6−1.2 × 10−4 M of D-PA with cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods, respectively. The detection limits (2σ) were determined as 3.0 × 10−5 and 3.5 × 10−6 M with CV and DPV, respectively. This method was also used for voltammetric determination of D-PA in pharmaceutical preparation by standard addition method.

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Authors and Affiliations

  1. Electroanalytical Chemical Research Laboratory, Faculty of Chemistry, Mazandaran University, Babolsar, Iran

    Jahan-Bakhsh Raoof, Reza Ojani, Mahsa Majidian & Fereshteh Chekin

Authors
  1. Jahan-Bakhsh Raoof
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  2. Reza Ojani
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  3. Mahsa Majidian
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  4. Fereshteh Chekin
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Published in Russian in Elektrokhimiya, 2010, Vol. 46, No. 12, pp. 1490–1496.

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Raoof, JB., Ojani, R., Majidian, M. et al. Voltammetric determination of D-penicillamine based on its homogeneous electrocatalytic oxidation with potassium iodide at the surface of glassy carbon electrode. Russ J Electrochem 46, 1395–1401 (2010). https://doi.org/10.1134/S1023193510120098

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  • DOI: https://doi.org/10.1134/S1023193510120098

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