Abstract
A theory is developed of square-wave voltammetry of the system in which both the reactant and the product of a simple electrode reaction are initially present in the electrolytic solution. A net response of fast and reversible electrode reaction depends on the sum of concentrations of reactant and product. Under this condition the ratio of maxima and minima of the components of net response can be used for the calculation of the ratio of concentrations of reactant and product. If the electrode reaction is kinetically controlled, the net response may split in two peaks. The potentials of these peaks can be used for the determination of transfer coefficients.
Similar content being viewed by others
References
Mirčeski, V., Komorsky-Lovrić, Š. and Lovrić, M., Square-wave voltammetry, Berlin: Springer, 2007.
Komorsky-Lovrić, Š. and Lovrić, M., in New Research on Electrochemistry, Vargus, E.P., Ed., New York: Nova Science Publishers, 2007, pp. 1–44.
Osteryoung, J. and O’Dea, J.J., in Electroanalytical Chemistry, Bard, A.J., Ed., Vol. 14, New York: Marcel Dekker, 1986, p. 209–308.
Eccles, G.N., Crit. Rev. Anal Chem., 1991, vol. 22, p. 345.
de Souza, D., Machado, S.A.S., and Avaca, L.A., Quim. Nova, 2003, vol. 26, p. 81.
de Souza, D., Codognoto, L., Malagutti, A.R., Toledo, R.A., Pedroso, V.A., Oliverira, R.T.S., Mazo, L.H., Avaca L.A., and Machado, S.A.S., Quim. Nova, 2004, vol. 27, p. 790.
Demortier, A. and Jehoulet, C., J. Electroanal. Chem., 1990, vol. 283, p. 15.
Weidner, J.W. and Fedkiw, P.S., Anal Chem., 1990, vol. 62, p. 875.
Keitghtley, A.M., Myland, J.C., Oldham, K.B., and Symons, P.G., J. Electroanal. Chem., 1992, vol. 322, p. 25.
Serna, C. and Molina, A., J. Electroanal Chem., 1999, vol. 466, p. 8.
Moreno, M.M. and Molina, A., Collect. Czech. Chem. Commun., 2005, vol. 70, p. 133.
Smit, W.M. and Wijnen, M.D., Rec. Trav. Chim. P. B., 1960, vol. 79, p. 5.
Wijnen, M.D. and Smit, W.M., Rec. Trav. Chim. P. B., 1960, vol. 79, p. 203.
Wijnen, M.D. and Smit, W.M., Rec. Trav. Chim. P. B., 1960, vol. 79, p. 289.
Barker, G.C., Anal. Chim. Acta, 1958, vol. 18, p. 118.
Brett, C.M.A. and Oliveira Brett, A.M., Electrochemistry, Oxford: Oxford University Press, 1998, pp. 412–420.
Fatouros, N. and Krulic, D., J. Electroanal. Chem., 2002, vol. 520, p. 1.
Fatouros, N., Krulic, D., and Larabi, N., J. Electroanal. Chem., 2004, vol. 568, p. 55.
Zelić, M., Croat. Chem. Acta, 2006, vol. 79, p. 49.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Elektrokhimiya, 2010, Vol. 46, No. 12, pp. 1465–1470.
The article is published in the original.
Rights and permissions
About this article
Cite this article
Komorsky-Lovrić, Š., Lovrić, M. Square-wave voltammetry of dissolved redox couple. Russ J Electrochem 46, 1373–1377 (2010). https://doi.org/10.1134/S1023193510120050
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193510120050