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Electroswitchable binding of [Co(dipy)3]3+ and [Fe(dipy)3]2+ n-sulfonato(thia)calix[4]arenas

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Abstract

The methods of cyclic voltammetry, electrolysis, and spectrophotometry were used to study electrochemical properties of (TCAS + Fe3+ + dipy), (CCAS + Fe3+ + dipy), and (CCAS + Fe3+ + [Co(dipy)3]3+) triple systems (where TCAS is n-sulfonatothiacalix[4]arene, CCAS is tetracarboxylate n-sulfonatocalix[4]arene, and dipy = α,α′-dipyridyl) in an aqueous solution. One-electron reduction of Fe(III) in the (TCAS + Fe3+ + dipy) system at pH 2.5 results in electroswitching of iron ions from the lower TCAS ring to the upper ([Fe(dipy)3]2+). Reverse electrochemical switching of the system is impossible due to mediator ([Fe(dipy)3]2+/3+) oxidation of TCAS. Reverse electroswitching of Fe(III) ions from unbound to bound state as ([Fe(dipy)3]2+) with CCAS has been revealed in the system (CCAS + Fe3+ + dipy) (pH 1.7) upon single-electron transfer, whereas reversible electroswitching by the upper rim of CCAS from one complex ion ([Co(dipy)3]3+) to another ([Fe(dipy)3]2+) has been demonstrated in the system ([Co(dipy)3]3+ + CCAS + Fe3+ upon double-electron transfer. In all systems, electric switching was accompanied by synchronous color switching.

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  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Russia

    V. V. Yanilkin, A. S. Stepanov, N. V. Nastapova, A. R. Mustafina, V. A. Burilov, S. E. Solov’eva, I. S. Antipin & A. I. Konovalov

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  1. V. V. Yanilkin
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  2. A. S. Stepanov
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  3. N. V. Nastapova
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  8. A. I. Konovalov
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Original Russian Text © V.V. Yanilkin, A.S. Stepanov, N.V. Nastapova, A.R. Mustafina, V.A. Burilov, S.E. Solov’eva, I.S. Antipin, A.I. Konovalov, 2010, published in Elektrokhimiya, 2010, Vol. 46, No. 11, pp. 1350–1367.

The paper was prepared for a special issue dedicated to the birth centenary of Ya.M. Kolotyrkin.

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Yanilkin, V.V., Stepanov, A.S., Nastapova, N.V. et al. Electroswitchable binding of [Co(dipy)3]3+ and [Fe(dipy)3]2+ n-sulfonato(thia)calix[4]arenas. Russ J Electrochem 46, 1263–1279 (2010). https://doi.org/10.1134/S1023193510110078

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