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Preparation and characterization of Li4/3Ti5/3O4/Ag composite prepared by sol-gel technique

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Abstract

The powders of Li4/3Ti5/3O4/Ag composite were prepared by sol-gel technique. Structural identification, surface morphology and electrochemical properties of the powders were studied by X-ray diffraction, scanning electron microscopy and galvanostatic charge-discharge experiments. The results show that Li4/3Ti5/3O4/Ag composite derived from sol-gel is a composite of Li4/3Ti5/3O4 and silver. Li4/3Ti5/3O4/Ag composite shows higher specific capacity, higher columbic efficiency and lower polarization than Li4/3Ti5/3O4. The addition of silver greatly improves the cycleability of Li4/3Ti5/3O4, especially at higher charge-discharge rate.

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References

  1. Ariyoshi, K., Yamato, R., and Ohzuku, T., Electrochim. Acta, 2005, vol. 51, p. 1125.

    Article  CAS  Google Scholar 

  2. Dokko, K., Sugaya, J., Nakano, H., Yasukawa, T., Matsue, T., and Kanamura, K., Electrochem. Comm., 2007, vol. 9, p. 857.

    Article  CAS  Google Scholar 

  3. Hardwick, L.J., Holzapfel, M., Novák, P., Dupont, L., and Baudrin, E., Electrochim. Acta, 2007, vol. 52, p. 5357.

    Article  CAS  Google Scholar 

  4. Whittingham, M.S. and Dines, M.B., J. Electrochem. Soc., 1997, vol. 124, p. 1387.

    Article  Google Scholar 

  5. Subramanian, V., Karki, A., and Gnanasekar, K.I., J. Power Sources, 2006, vol. 159, p. 186.

    Article  CAS  Google Scholar 

  6. Ohzuku, T., Ueda, A., and Yamamoto, N., J. Electrochem. Soc., 1995, vol. 142, p. 1431.

    Article  CAS  Google Scholar 

  7. Ariyoshi, K., Iwata, E., Kuniyoshi, M., Wakabayashi, H., and Ohzuku, T., Electrochem. Solid-State Lett., 2006, vol. 9, p. A557.

    Article  CAS  Google Scholar 

  8. Allen, G. C. and Paul, M., Appl. Spectrosc., 1995, vol. 49, p. 451.

    Article  CAS  Google Scholar 

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Correspondence to Xian Ming Wu.

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Wu, X.M., Li, R.X., Chen, S. et al. Preparation and characterization of Li4/3Ti5/3O4/Ag composite prepared by sol-gel technique. Russ J Electrochem 46, 1007–1010 (2010). https://doi.org/10.1134/S1023193510090065

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  • DOI: https://doi.org/10.1134/S1023193510090065

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