Abstract
The powders of Li4/3Ti5/3O4/Ag composite were prepared by sol-gel technique. Structural identification, surface morphology and electrochemical properties of the powders were studied by X-ray diffraction, scanning electron microscopy and galvanostatic charge-discharge experiments. The results show that Li4/3Ti5/3O4/Ag composite derived from sol-gel is a composite of Li4/3Ti5/3O4 and silver. Li4/3Ti5/3O4/Ag composite shows higher specific capacity, higher columbic efficiency and lower polarization than Li4/3Ti5/3O4. The addition of silver greatly improves the cycleability of Li4/3Ti5/3O4, especially at higher charge-discharge rate.
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Ariyoshi, K., Yamato, R., and Ohzuku, T., Electrochim. Acta, 2005, vol. 51, p. 1125.
Dokko, K., Sugaya, J., Nakano, H., Yasukawa, T., Matsue, T., and Kanamura, K., Electrochem. Comm., 2007, vol. 9, p. 857.
Hardwick, L.J., Holzapfel, M., Novák, P., Dupont, L., and Baudrin, E., Electrochim. Acta, 2007, vol. 52, p. 5357.
Whittingham, M.S. and Dines, M.B., J. Electrochem. Soc., 1997, vol. 124, p. 1387.
Subramanian, V., Karki, A., and Gnanasekar, K.I., J. Power Sources, 2006, vol. 159, p. 186.
Ohzuku, T., Ueda, A., and Yamamoto, N., J. Electrochem. Soc., 1995, vol. 142, p. 1431.
Ariyoshi, K., Iwata, E., Kuniyoshi, M., Wakabayashi, H., and Ohzuku, T., Electrochem. Solid-State Lett., 2006, vol. 9, p. A557.
Allen, G. C. and Paul, M., Appl. Spectrosc., 1995, vol. 49, p. 451.
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Wu, X.M., Li, R.X., Chen, S. et al. Preparation and characterization of Li4/3Ti5/3O4/Ag composite prepared by sol-gel technique. Russ J Electrochem 46, 1007–1010 (2010). https://doi.org/10.1134/S1023193510090065
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DOI: https://doi.org/10.1134/S1023193510090065