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On the applying of fluctuation theorems to the theory of slow discharge in galvanostatic regime

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Abstract

Expressions for the equation of slow discharge in galvanostatic regime are drawn, as power expansion with respect to overvoltage, in terms of the Bochkov-Kuzovlev and Jarzynski fluctuation theorems combined with the Stratonovich relations for nonlinear nonequilibrium thermodynamics. Coefficients of the expansion are linear functions of the intensities of cumulant correlation functions that characterize the electrode potential fluctuations.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    B. M. Grafov

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  1. B. M. Grafov
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Correspondence to B. M. Grafov.

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Original Russian Text © B.M. Grafov, 2010, published in Elektrokhimiya, 2010, Vol. 46, No. 8, pp. 1009–1012.

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Grafov, B.M. On the applying of fluctuation theorems to the theory of slow discharge in galvanostatic regime. Russ J Electrochem 46, 948–951 (2010). https://doi.org/10.1134/S1023193510080136

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  • DOI: https://doi.org/10.1134/S1023193510080136

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